Highly efficient and expeditious PdO/SBA-15 catalysts for allylic oxidation of cyclohexene to cyclohexenone

被引：49

作者：

Ganji, Saidulu ^{[1
]}

Bukya, Padma ^{[1
]}

Vakati, Venkateswarlu ^{[1
]}

Rao, Kamaraju Seetha Rama ^{[1
]}

Burri, David Raju ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Catalysis Lab, Hyderabad 500607, Andhra Pradesh, India

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2013年 / 3卷 / 02期

关键词：

AEROBIC OXIDATION; SELECTIVE OXIDATION; MESOPOROUS SILICA; MOLECULAR-OXYGEN; ALCOHOLS; COMPLEXES; EPOXIDATION; ACTIVATION; KETONES; SURFACE;

D O I：

10.1039/c2cy20627g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of four PdO/SBA-15 catalysts with 1, 2, 4, 5% (by weight) loading of PdO have been prepared by a conventional impregnation method and are characterized by N-2-adsorption, low-angle and wide-angle XRD, XPS and TEM techniques. The catalysts exhibited very high conversion of cyclohexene and high selectivity of cyclohexenone with 70% t-BuOOH in CH3CN. The structural and textural characteristics of catalysts play a crucial role in high conversion and selectivity.

引用

页码：409 / 414

页数：6

共 44 条

[1] PALLADIUM(II)-MEDIATED OXIDATION OF ALCOHOLS USING 1,2-DICHLOROETHANE AS PD(0) REOXIDANT [J].

AITMOHAND, S ;

HENIN, F ;

MUZART, J .

TETRAHEDRON LETTERS, 1995, 36 (14) :2473-2476

[2]

Blackburn T.F., 1977, J CHEM SOC, P157, DOI DOI 10.1039/C39770000157

[3] Formation of short In2O3 nanorod Arrays within mesoporous silica [J].

Chang, Shih-Chieh ;

Huang, Michael H. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (07) :2304-2307

[4] Efficient allylic oxidation of cyclohexene with oxygen catalyzed by chloromethylated polystyrene supported tridentate Schiff-base complexes [J].

Chang, Yue ;

Lv, Yurong ;

Lu, Feng ;

Zha, Fei ;

Lei, Zigiang .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2010, 320 (1-2) :56-61

[5] Immobilization of Fe, Mn and Co tetraphenylporphyrin complexes in MCM-41 and their catalytic activity in cyclohexene oxidation reaction by hydrogen peroxide [J].

Costa, Andreia A. ;

Ghesti, Grace F. ;

de Macedo, Julio L. ;

Braga, Valdeilson S. ;

Santos, Marcello M. ;

Dias, Jose A. ;

Dias, Silvia C. L. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 282 (1-2) :149-157

[6] Solvent-free allylic oxidation of cycloolefins over mesoporous CrMCM-41 molecular sieve catalyst at 1 atm dioxygen [J].

Dapurkar, Sudhir E. ;

Kawanami, Hajime ;

Komura, Kenichi ;

Yokoyama, Toshirou ;

Ikushima, Yutaka .

APPLIED CATALYSIS A-GENERAL, 2008, 346 (1-2) :112-116

[7] Synthesis, characterization and selective oxidation properties of Ti-containing mesoporous catalysts [J].

Eimer, GA ;

Casuscelli, SG ;

Ghione, GE ;

Crivello, ME ;

Herrero, ER .

APPLIED CATALYSIS A-GENERAL, 2006, 298 :232-242

[8] Cu(II)-and Co(II)-containing metal-organic frameworks (MOFs) as catalysts for cyclohexene oxidation with oxygen under solvent-free conditions [J].

Fu, Yanghe ;

Sun, Dengrong ;

Qin, Meng ;

Huang, Renkun ;

Li, Zhaohui .

RSC ADVANCES, 2012, 2 (08) :3309-3314

[9] Efficient allylic oxidation of cyclohexene catalyzed by trimetallic hybrid nano-mixed oxide (Ru/Co/Ce) [J].

Ghiaci, Mehran ;

Aghabarari, Behzad ;

Botelho do Rego, A. M. ;

Ferraria, A. M. ;

Habibollahi, Saeed .

APPLIED CATALYSIS A-GENERAL, 2011, 393 (1-2) :225-230

[10] Allylic oxidation of cyclohexene over silica immobilized iron tetrasulfophthalocyanine [J].

Gonzalez, Lina M. ;

de P, Aida L. Villa ;

de C, Consuelo Montes ;

Sorokin, Alexander .

TETRAHEDRON LETTERS, 2006, 47 (36) :6465-6468

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