Preparation and Interfacial Properties of Phosphonic Acid-Terminated Self-Assembled Monolayers on Gold Surface

被引：34

作者：

Chen, Yu ^{[1
]}

Yang, Xiao-Jing ^{[1
]}

Jin, Bo ^{[2
]}

Guo, Li-Rong ^{[1
]}

Zheng, Li-Min ^{[1
]}

Xia, Xing-Hua ^{[2
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

[2] Nanjing Univ, Key Lab Analyt Chem Life Sci, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2009年 / 113卷 / 11期

关键词：

QUARTZ-CRYSTAL MICROBALANCE; AU(111) SINGLE-CRYSTAL; CYCLIC VOLTAMMETRY; MOLECULAR FILMS; CARBOXYLIC-ACID; ELECTROCHEMICAL CHARACTERIZATION; ELECTROLESS DEPOSITION; TITRATION; ADSORPTION; STABILITY;

D O I：

10.1021/jp808195j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The preparation and interfacial properties of self-assembled monolayers (SAMs) of 3-mercaptopropylphosphonic acid [HS-(CH2)(3)-PO3H2, MPPA] adsorbed on Au surfaces have been systematically investigated with the electrochemical method, X-ray photoelectron spectroscopy (XPS), and surface-enhanced internal reflection infrared spectroscopy measurements. An improved rinse method (base-acid rinse protocol) is presented to prepare the MPPA monolayers free of unbound MPPA thiols. Experimental results show that the effect of the degree of dissociation of -PO3H2 groups on the compactness of MPPA-SAMs is nonlinear possibly because of hydrogen bond interaction and the dibasic nature and hydrophilicity of the -PO3H2 groups. The effects of pH and the electric field on the surface charge of MPPA-SAMs are investigated.

引用

页码：4515 / 4521

页数：7

共 65 条

[31] High-resolution STM and XPS studies of thiophene self-assembled monolayers on Au(111) [J].

Noh, J ;

Ito, E ;

Nakajima, K ;

Kim, J ;

Lee, H ;

Hara, M .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (29) :7139-7141

[32] Loosely packed self-assembled monolayers on gold generated from 2-alkyl-2-methylpropane-1,3-dithiols [J].

Park, JS ;

Smith, AC ;

Lee, TR .

LANGMUIR, 2004, 20 (14) :5829-5836

[33] 1H fast MAS NMR studies of hydrogen-bonding interactions in self-assembled monolayers [J].

Pawsey, S ;

McCormick, M ;

De Paul, S ;

Graf, R ;

Lee, YS ;

Reven, L ;

Spiess, HW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (14) :4174-4184

[34] Metal ion interaction with phosphorylated tyrosine analogue monolayers on gold [J].

Petoral, Rodrigo M., Jr. ;

Bjorefors, Fredrik ;

Uvdal, Kajsa .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (46) :23410-23416

[35]

Pomales G.S., 2007, J ELECTROANAL CHEM, V611, P80

[36] SELF-ASSEMBLY OF ORGANIC MULTILAYERS WITH POLAR ORDER USING ZIRCONIUM-PHOSPHATE BONDING BETWEEN LAYERS [J].

PUTVINSKI, TM ;

SCHILLING, ML ;

KATZ, HE ;

CHIDSEY, CED ;

MUJSCE, AM ;

EMERSON, AB .

LANGMUIR, 1990, 6 (10) :1567-1571

[37] Electrochemical studies of 6-mercaptonicotinic acid monolayer on Au electrode [J].

Raj, CR ;

Behera, S .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2005, 581 (01) :61-69

[38]

ROOTH M, 2007, PHYS CHEM CHEM PHYS, V111, P15363

[39] Interfacial pH and surface pKa of a thioctic acid self-assembled monolayer [J].

Rooth, Maxim ;

Shaw, Andrew M. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (41) :4741-4743

[40] Electrochemical and infrared spectroscopy studies of 4-mercaptobenzoic acid SAMS on gold surfaces [J].

Rosendahl, Scott M. ;

Burgess, Ian J. .

ELECTROCHIMICA ACTA, 2008, 53 (23) :6759-6767

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