Preparation and Interfacial Properties of Phosphonic Acid-Terminated Self-Assembled Monolayers on Gold Surface

被引：34
作者：
Chen, Yu [1 ]
Yang, Xiao-Jing [1 ]
Jin, Bo [2 ]
Guo, Li-Rong [1 ]
Zheng, Li-Min [1 ]
Xia, Xing-Hua [2 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China
[2] Nanjing Univ, Key Lab Analyt Chem Life Sci, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2009年 / 113卷 / 11期
关键词：
QUARTZ-CRYSTAL MICROBALANCE; AU(111) SINGLE-CRYSTAL; CYCLIC VOLTAMMETRY; MOLECULAR FILMS; CARBOXYLIC-ACID; ELECTROCHEMICAL CHARACTERIZATION; ELECTROLESS DEPOSITION; TITRATION; ADSORPTION; STABILITY;
D O I：
10.1021/jp808195j
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The preparation and interfacial properties of self-assembled monolayers (SAMs) of 3-mercaptopropylphosphonic acid [HS-(CH2)(3)-PO3H2, MPPA] adsorbed on Au surfaces have been systematically investigated with the electrochemical method, X-ray photoelectron spectroscopy (XPS), and surface-enhanced internal reflection infrared spectroscopy measurements. An improved rinse method (base-acid rinse protocol) is presented to prepare the MPPA monolayers free of unbound MPPA thiols. Experimental results show that the effect of the degree of dissociation of -PO3H2 groups on the compactness of MPPA-SAMs is nonlinear possibly because of hydrogen bond interaction and the dibasic nature and hydrophilicity of the -PO3H2 groups. The effects of pH and the electric field on the surface charge of MPPA-SAMs are investigated.
引用
收藏
页码：4515 / 4521
页数：7
相关论文
共 65 条
[1]   Immobilization of peroxidase glycoprotein on gold electrodes modified with mixed epoxy-boronic acid monolayers [J].
Abad, JM ;
Vélez, M ;
Santamaría, C ;
Guisán, JM ;
Matheus, PR ;
Vázquez, L ;
Gazaryan, I ;
Gorton, L ;
Gibson, T ;
Fernández, VM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (43) :12845-12853
[2]   Investigating the thermodynamic causes behind the anomalously large shifts in pKa values of benzoic acid-modified graphite and glassy carbon surfaces [J].
Abiman, Poobalasingam ;
Crossley, Alison ;
Wildgoose, Gregory G. ;
Jones, John H. ;
Compton, Richard G. .
LANGMUIR, 2007, 23 (14) :7847-7852
[3]   Oriented growth of calcite controlled by self-assembled monolayers of functionalized alkanethiols supported on gold and silver [J].
Aizenberg, J ;
Black, AJ ;
Whitesides, GH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) :4500-4509
[4]   DISCRETENESS-OF-CHARGE EFFECTS AT MOLECULAR FILMS CONTAINING ACID/BASE GROUPS [J].
ANDREU, R ;
FAWCETT, WR .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (48) :12753-12758
[5]   Voltammetric detection of inorganic phosphate using ion-channel sensing with self-assembled monolayers of a hydrogen bond-forming receptor [J].
Aoki, H ;
Hasegawa, K ;
Tohda, K ;
Umezawa, Y .
BIOSENSORS & BIOELECTRONICS, 2003, 18 (2-3) :261-267
[6]  
BARD AJ, 2000, ELECTROCHEMICAL METH, P625
[7]   Gold-sulfur bonding in 2D and 3D self-assembled monolayers: XPS characterization [J].
Bourg, MC ;
Badia, A ;
Lennox, RB .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (28) :6562-6567
[8]   Electric field driven protonation/deprotonation of self-assembled monolayers of acid-terminated thiols [J].
Burgess, I ;
Seivewright, B ;
Lennox, RB .
LANGMUIR, 2006, 22 (09) :4420-4428
[9]   N-hydroxysuccinimide-terminated self-assembled monolayers on gold for biomolecules immobilisation [J].
Cabrita, JF ;
Abrantes, LM ;
Viana, AS .
ELECTROCHIMICA ACTA, 2005, 50 (10) :2117-2124
[10]   Characterization of alkanethiol-self-assembled monolayers-modified gold electrodes by electrochemical impedance spectroscopy [J].
Campuzano, S ;
Pedrero, M ;
Montemayor, C ;
Fatás, E ;
Pingarrón, JM .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2006, 586 (01) :112-121
1234567