Tritellurasumanene: ultrasound assisted one-pot synthesis and extended valence adducts with bromine

被引：54

作者：

Wang, Shitao ^{[1
]}

Li, Xuexiang ^{[1
]}

Hou, Xueqing ^{[1
]}

Sun, Yantao ^{[1
]}

Shao, Xiangfeng ^{[1
]}

机构：

[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Tianshui Southern Rd 222, Lanzhou, Gansu, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 100期

基金：

中国国家自然科学基金;

关键词：

DOPED GRAPHITIC CARBON; CONJUGATED POLYMERS; PI-BOWL; SUMANENE; TELLURIUM; CHEMISTRY; TELLUROPHENES; SELENIUM; COMPLEX; TRICHALCOGENASUMANENE;

D O I：

10.1039/c6cc08170c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tritellurasumanene is synthesized from a triphenylene skeleton via ultrasound assisted one-pot reaction. This compound adopts a flat conjugated system and displays Te center dot center dot center dot Te (3.83 angstrom) interactions in the solid state. Its optical properties and chemical reactivity are quite different from those of its trithia- and triselena-analogues.

引用

页码：14486 / 14489

页数：4

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