A 2,2′-bipyridine coordination complex of [ICl2]+

被引：6

作者：

Shaw, Andrew J. M. ^{[1
]}

Corbo, Robert ^{[1
]}

Wilson, David J. D. ^{[1
]}

Dutton, Jason L. ^{[1
]}

机构：

[1] La Trobe Univ, La Trobe Inst Mol Sci, Dept Chem, Melbourne, Vic, Australia

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 34期

关键词：

PYRIDINE; CL; TETRAHALIDES; ACTIVATION; CHEMISTRY; OXIDATION; REAGENTS; ADDUCTS; LIGANDS; SE;

D O I：

10.1039/c4dt03549f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The formation of a new class of I(III) compound is reported; an N,N' chelated iodine cation ([bpy-ICl2](+); bpy = 2,2'-bipyridine). The complex is obtained as an [ICl4](-) salt and is formed via simple reaction of bpy with ICl3. The compound is relatively unstable, but may be stored as a solid and is shown to be competent in the oxidative chlorination of Au(I)-NHC complexes.

引用

页码：15083 / 15087

页数：5

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