SBA-15(P)-Supported tetraethylenepentamine for CO2 Capture

被引:3
作者
Yang, Yonghong [1 ]
Yang, Cheng [1 ]
Wu, Jinhu [1 ]
机构
[1] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China
来源
ADVANCED MATERIALS AND ENGINEERING MATERIALS, PTS 1 AND 2 | 2012年 / 457-458卷
关键词
SBA-15(P); TEPA; CO2; Dynamic impregnation; Stability; MESOPOROUS MOLECULAR-SIEVE; ADSORPTION;
D O I
10.4028/www.scientific.net/AMR.457-458.1283
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, various amine-modified CO2 adsorbents were prepared by incorporating tetraethylenepenthamine (TEPA) onto SBA-15(P) by controlling dynamic impregnation process. The materials were characterized by X-ray diffraction (XRD), nitrogen adsorption/desorption, elemental analysis (EA) and Fourier transform infrared (FT-IR) experiments. Moreover, the adsorption capacities and cycle life were evaculated by CO2 temperature programmed desorption (CO2-TPD). Various characterization results indicate that the morphology and loading amount of TEPA on the support material were controlled by adjusting dynamic impregnation times. Under given conditions, there is an optimum dynamic impregnation times.
引用
收藏
页码:1283 / 1286
页数:4
相关论文
共 7 条
[1]   In-situ infrared study of CO2 adsorption on SBA-15 grafted with γ-(aminopropyl)triethoxysilane [J].
Chang, ACC ;
Chuang, SSC ;
Gray, M ;
Soong, Y .
ENERGY & FUELS, 2003, 17 (02) :468-473
[2]   Amine-grafted MCM-48 and silica xerogel as superior sorbents for acidic gas removal from natural gas [J].
Huang, HY ;
Yang, RT ;
Chinn, D ;
Munson, CL .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (12) :2427-2433
[3]   Surface functionalization and stabilization of mesoporous silica spheres by silanization and their adsorption characteristics [J].
Matsumoto, A ;
Tsutsumi, K ;
Schumacher, K ;
Unger, KK .
LANGMUIR, 2002, 18 (10) :4014-4019
[4]   Preparation and characterization of novel CO2 "molecular basket" adsorbents based on polymer-modified mesoporous molecular sieve MCM-41 [J].
Xu, XC ;
Song, CS ;
Andrésen, JM ;
Miller, BG ;
Scaroni, AW .
MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 62 (1-2) :29-45
[5]   Novel polyethylenimine-modified mesoporous molecular sieve of MCM-41 type as high-capacity adsorbent for CO2 capture [J].
Xu, XC ;
Song, CS ;
Andresen, JM ;
Miller, BG ;
Scaroni, AW .
ENERGY & FUELS, 2002, 16 (06) :1463-1469
[6]   Grafting Morphologies of TEPA on SBA-15(P) and Its Effect on CO2 Adsorption Performance [J].
Yang Yong-Hong ;
Li Fen-Fen ;
Yang Cheng ;
Zhang Wen-Yu ;
Wu Jin-Hu .
ACTA PHYSICO-CHIMICA SINICA, 2012, 28 (01) :195-200
[7]   Adsorption behavior of arsenate at transition metal cations captured by amino-functionalized mesoporous silicas [J].
Yoshitake, H ;
Yokoi, T ;
Tatsumi, T .
CHEMISTRY OF MATERIALS, 2003, 15 (08) :1713-1721