Silver(I) coordination polymer based on anthraquinone-2,6-disulfonate: synthesis, crystal structure, and luminescent properties

被引：2

作者：

Hou, Xiang-Yang ^{[1
]}

Wang, Xiao ^{[1
]}

Fu, Feng ^{[1
]}

Wang, Ji-Jiang ^{[1
]}

Tang, Long ^{[1
]}

Wu, Ya-Pan ^{[1
]}

机构：

[1] Yanan Univ, Dept Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Shaanxi, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 65卷 / 16期

关键词：

Silver; Sulfonate; Polymers; Fluorescence; METAL-ORGANIC FRAMEWORKS; HYDROTHERMAL SYNTHESIS; COMPLEXES; LIGANDS; AG(I);

D O I：

10.1080/00958972.2012.707315

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Self-assembly of anthraquinone-2,6-disulfonic acid disodium salt (Na(2)a-2,6-dad) and AgNO3 under hydrothermal conditions resulted in an unprecedented coordination complex, which was characterized by single-crystal X-ray analyses, elemental analyses, IR spectra, TG analyses, and fluorescence investigations. Complex 1 is a 3-D coordination polymer, where a-2,6-dad and Ag-Ag bonds play vital roles. Two sulfonate groups of a-2,6-dad are mu(4)- and mu(5)-bridges. The unique packing environments of the Ag ions and Ag-Ag bonds lead to 1-D chains consisting of eight-and four-membered rings for Ag1 and Ag1, Ag2 and Ag2 connection, respectively.

引用

页码：2935 / 2944

页数：10

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