Rh-Catalyzed Diarylamine Synthesis by Intermolecular C-H Amination of Heteroarylarenes

被引：37
作者：
Tang, Conghui [1 ]
Yuan, Yizhi [1 ]
Cui, Yuxin [1 ]
Jiao, Ning [1 ,2 ]
机构：
[1] Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
[2] Peking Univ, Shenzhen Grad Sch, Sch Chem Biol & Biotechnol, Lab Chem Genom, Shenzhen 518055, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 2013卷 / 33期
基金：
中国国家自然科学基金;
关键词：
C-H activation; Rhodium; Amination; Azides; N BOND FORMATION; COUPLING REACTIONS; ARYL AZIDES; COPPER; AMIDATION; PALLADIUM; ARENES; FUNCTIONALIZATION; CHLOROAMINES; ACTIVATION;
D O I：
10.1002/ejoc.201301430
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel and efficient Rh-catalyzed intermolecular C-H amination of heteroarylarenes with aryl azides has been developed. This procedure does not require an oxidant, releases N-2 as the only byproduct, and provides an efficient approach to diarylamines with broad functional-group tolerance.
引用
收藏
页码：7480 / 7483
页数：4
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