Facile fabrication of ordered mesoporous Bi/Ti-MCM-41 nanocomposites for visible light-driven photocatalytic degradation of methylene blue and CO oxidation

被引:25
作者
Mohamed, Shaimaa K. [1 ]
Ibrahim, Amr Awad [2 ,3 ]
Mousa, A. A. [1 ]
Betiha, Mohamed A. [4 ,5 ]
El-Sharkawy, E. A. [1 ]
Hassan, Hassan M. A. [1 ,5 ]
机构
[1] Suez Univ, Fac Sci, Dept Chem, Suez, Egypt
[2] Mansoura Univ, Fac Sci, Dept Chem, Mansoura, Egypt
[3] Virginia Commonwealth Univ, Dept Chem, Richmond, VA 23284 USA
[4] Egyptian Petr Res Inst, Cairo 11727, Egypt
[5] Cairo Univ, Egypt Nanotechnol Ctr EGNC, El Sheikh Zayed Campus, Giza 12588, Egypt
关键词
Mesoporous; Ti-MCM-41; Bi/Ti-MCM-41; composite; Carbon monoxide oxidation; Visible photocatalyst; TITANIA NANOPARTICLES; ROOM-TEMPERATURE; PHOTODEGRADATION; PERFORMANCE; PARTICLES; BENZENE; OXIDE; UV;
D O I
10.1016/j.seppur.2017.12.008
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Bi/Ti-MCM-41 nanocomposite was fabricated by a simple one-step impregnating approach. The composites have been exploited, for the first time, as a dual function catalyst for low-temperature CO oxidation under aerobic condition and a visible-light-driven photocatalyst for degradation of MB as organic pollutants. The promoting effect of bismuth species on Ti-MCM-41 has been investigated with the influence of introduced various Bi amount. It worth noting that the hexagonal mesostructured of Ti-MCM-41 remained unaltered and were not interrupted during the Bi deposition process. The bismuth species dispersed well and incorporated both within the mesochannel and the pore wall of Ti-MCM-41. The fabricated composite catalyst showed a significant catalytic performance compared to pristine Ti-MCM-41. The significant enhancement of the photodegradation performance of the Bi/Ti-MCM-41 composite could be assigned to the synergistic effects of interfaces between Bi2O3 species and TiO2. Therefore, the fabricated composite catalyst is a promising candidate for environmental applications.
引用
收藏
页码:174 / 183
页数:10
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