Water-based synthesis and sensing application of polyallylamine functionalized platinum nanodendrite assemblies

被引:10
作者
Qiu, Xiaoyu [1 ]
Fu, Gengtao [1 ]
Zhao, Yue [1 ]
Tang, Yawen [1 ]
Chen, Yu [1 ]
Lu, Tianhong [1 ]
机构
[1] Nanjing Normal Univ, Jiangsu Key Lab New Power Batteries, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Coll Chem & Mat Sci, Nanjing 210023, Jiangsu, Peoples R China
关键词
SUPERIOR ELECTROCATALYTIC ACTIVITY; OXYGEN REDUCTION REACTION; WALLED CARBON NANOTUBES; ONE-POT; TOLERANT ABILITY; GREEN SYNTHESIS; NANOPARTICLES; OXIDATION; NANOCUBES; SHAPE;
D O I
10.1039/c3ta13218h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Here we report a facile chemical reduction route to synthesize polyallylamine (PAH) functionalized platinum nanodendrite assemblies (Pt-NDAs). Based on an aggregation directed nanocrystal rapid growth mechanism, phosphoric acid induced attachment of single PAH functionalized nanodendrite is responsible for the formation of self-assembled morphology. The PAH functionalization endows Pt-NDAs with particular self-assembly ability on the glassy carbon (GC) electrode. The Pt-NDAs self-assembled on the GC electrode exhibit excellent electrocatalytic activity for the nitrite oxidation, and thus can be used as an electrochemical sensor for nitrite detection.
引用
收藏
页码:14874 / 14878
页数:5
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