Effect of manganese(III) Schiff base complexes on the hydrolysis of p-nitrophenyl picolinate

被引：6

作者：

Xu, Bin ^{[1
]}

Jiang, Weidong ^{[1
]}

Zhang, Jin ^{[2
]}

Tang, Ying ^{[2
]}

Li, Jianzhang ^{[1
]}

机构：

[1] Sichuan Univ Sci & Engn, Sch Chem & Pharmaceut Engn, Key Lab Green Chem & Technol, Zigong 643000, Sichuan, Peoples R China

[2] Chongqing Univ Arts & Sci, Dept Chem & Environm Sci, Chongqing 402160, Yongchuan, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2009年 / 34卷 / 03期

关键词：

GEMINI SURFACTANT MICELLES; CARBOXYLIC-ACID ESTERS; BINUCLEAR METALLOHYDROLASES; CLEAVAGE; METALLOMICELLES; CATALYSTS; PHOSPHATE; LIGANDS; NI(II);

D O I：

10.1007/s11243-009-9193-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two mono-Schiff base Mn(III) complexes were used to catalyze the hydrolysis of p-nitrophenyl picolinate (PNPP) in micellar solutions of n-lauroylsarcosine sodium (LSS) and polyoxyethylene(23) lauryl ether (Brij35). The results show that both catalysts enhance the hydrolysis of PNPP by over two orders of magnitude relative to the spontaneous rate at 25 A degrees C. Moreover, Mn(III)-promoted hydrolysis of PNPP was faster in LSS micellar solution than in both Brij35 micellar solution and pure buffer.

引用

收藏

页码：293 / 296

页数：4

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