Direct Electrospinning of Cellulose-Chitosan Composite Nanofiber

被引:21
作者
Devarayan, Kesavan [1 ]
Hanaoka, Hirokatsu [1 ]
Hachisu, Masakazu [2 ]
Araki, Jun [3 ]
Ohguchi, Masakatsu [4 ]
Behera, Bijoya Kumar [5 ]
Ohkawa, Kousaku [1 ]
机构
[1] Shinshu Univ, Inst High Polymer Res, Fac Text Sci & Technol, Ueda, Nagano 3868567, Japan
[2] Natl Inst Adv Ind Sci & Technol, Res Inst Genome Based Biofactory, Toyohira Ku, Sapporo, Hokkaido 0628517, Japan
[3] Shinshu Univ, Div Chem & Mat, Fac Text Sci & Technol, Funct Polymer Sci Course, Ueda, Nagano 3868567, Japan
[4] Shinshu Univ, Innovat Ctr Adv Interdisciplinary Res Areas, Ueda, Nagano 3868567, Japan
[5] Indian Inst Technol, Dept Text Technol, New Delhi 110016, India
关键词
cellulose; chitosan; electrospinning; nanocomposites; nanofibers; FIBERS; MEMBRANES; POLYMER;
D O I
10.1002/mame.201200337
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The direct electrospinning of a non-derivatized cellulose (Cs)-chitosan (Ch) composite nanofiber is described for the first time. Either of two cellulose preparations from different sources, i.e., cotton (Cs-C) or bamboo (Cs-B), is fabricated into composite electrospun non-woven fabrics (ESNWs) with Ch using the trifluoroacetic acid-acetic acid mixed solvent. The total concentration of Cs+Ch in the mixed solvent is fixed at 4.0wt.-% with various Cs/Ch weight ratios of 8:2, 5:5 (Figure shows Cs-B/Ch-ESNW), and 2:8, which are fabricated into fine fibers in the Cs/Ch-ESNWs having average diameters mostly <100nm. The treatment of the composite fibers with an alkaline-alcohol solution produces the water-resistant ESNWs, which can retain their fine fibrous network in aqueous environments.
引用
收藏
页码:1059 / 1064
页数:6
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