DBU, a highly efficient reagent for the facile regeneration of (hetero)arylamines from their acetamides and benzamides: Influence of solvent, temperature, and microwave irradiation

被引：19

作者：

Chakrabarty, M

Ghosh, N

Khasnobis, S

Chakrabarty, M

机构：

[1] Bose Inst, Dept Chem, Kolkata 700009, W Bengal, India

[2] Acharya JC Bose Coll, Dept Chem, Kolkata 700020, W Bengal, India

[3] Bethune Coll, Dept Chem, Kolkata 700006, W Bengal, India

来源：

SYNTHETIC COMMUNICATIONS | 2002年 / 32卷 / 02期

关键词：

D O I：

10.1081/SCC-120002011

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) was found to smoothly cleave the N-acetyl and N-benzoyl derivatives of carbazoles, indoles and nitroanilines quickly in refluxing methanol and the parent amines were recovered in excellent yields. Complete cleavage could also be accomplished in acetonitrile solution under reflux and also under microwave irradiation, which, however, required considerably longer periods.

引用

页码：265 / 272

页数：8

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