Direct nucleophilic fluorination of carbonyl groups of benzophenones and benzils with Deoxofluor

被引：36

作者：

Chang, Ying ^{[1
]}

Tewari, Amit ^{[1
]}

Adi, Avi-Izak ^{[1
]}

Bae, Chulsung ^{[1
]}

机构：

[1] Univ Nevada, Dept Chem, Las Vegas, NV 89154 USA

来源：

TETRAHEDRON | 2008年 / 64卷 / 42期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/j.tet.2008.08.009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The carbonyl groups of diaryl ketones and diaryl diketones were directly fluorinated with bis(2-methoxyethyl)aminosulfur trifluoride (Deoxofluor) under neat conditions to give the Corresponding gem-difluorides and tetrafluorinated derivatives in moderate to high yields. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：9837 / 9842

页数：6

共 42 条

[1]

Banks R.E, 1982, PREPARATION PROPERTI

[2]

Banks R.E., 1994, ORGANOFLUORINE CHEM

[3]

BOSWELL GA, 1974, ORG REACTIONS, V21, P20, DOI DOI 10.1002/0471264180.OR021.01

[4] Solvent effect on intramolecular hydrogen bonds in push-pull conjugated molecules [J].