Synthesis and luminescence properties of Eu3+ doped BaGd2Ti4O13 phosphors

被引：21

作者：

Lee, Soo Hyun ^{[1
]}

Yu, Jae Su ^{[1
]}

机构：

[1] Kyung Hee Univ, Inst Laser Engn, Dept Elect & Radio Engn, Yongin 446701, Gyeonggi, South Korea

来源：

MATERIALS RESEARCH BULLETIN | 2014年 / 50卷

基金：

新加坡国家研究基金会;

关键词：

Inorganic compounds; Optical materials; Sol-gel chemistry; X-ray diffraction; Luminescence; ELECTRONIC-ENERGY LEVELS; LANTHANIDE AQUO IONS; PHOTOLUMINESCENCE; SM3+;

D O I：

10.1016/j.materresbull.2013.11.009

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We synthesized the trivalent europium ions (Eu3+) doped BaGd2Ti4O13 (BGT) phosphors by a sol-gel method and investigated their luminescence properties by varying the dopant concentration. The BGT host material showed the pure orthorhombic phase after annealing at 1350 C for 40 h. The photoluminescence (PL) emission of BGT:Eu3+ phosphors exhibited D-5(0) -> F-7(J) (=) (1,2,3,4) transitions, resulting in the reddish-orange color under 395 nm of excitation wavelength. From the PL results, an optimized doping concentration of Eu3+ ions was found to be at 8 mol%. The obtained cathodoluminescence spectra were similar to the PL spectra. The BGT:Eu3+ phosphors can help to emit a natural white light for near-ultraviolet and visible excitation wavelengths based white light-emitting diodes. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：354 / 358

页数：5

共 22 条

[1] Self-Assembled Columnar Structure Gd2O3:Eu3+: Solvothermal Synthesis and Luminescence Properties [J].

Bi, Huifang ;

Li, Xia .

INTEGRATED FERROELECTRICS, 2012, 135 :119-124

[2] ELECTRONIC ENERGY LEVELS IN TRIVALENT LANTHANIDE AQUO IONS .I. PR3+ ND3+ PM3+ SM3+ DY3+ HO3+ ER3+ AND TM3+ [J].

CARNALL, WT ;

FIELDS, PR ;

RAJNAK, K .

JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (10) :4424-&

[3]

CARNALL WT, 1968, J CHEM PHYS, V49, P4447, DOI 10.1063/1.1669895

[4] Nanocrystalline CaYAlO4:Tb3+/Eu3+ as promising phosphors for full-color field emission displays [J].

Geng, Dongling ;

Li, Guogang ;

Shang, Mengmeng ;

Peng, Chong ;

Zhang, Yang ;

Cheng, Ziyong ;

Lin, Jun .

DALTON TRANSACTIONS, 2012, 41 (10) :3078-3086

[5] Structure and site selective luminescence of sol-gel derived Eu:Sr2SiO4 [J].

Gupta, S. K. ;

Mohapatra, M. ;

Kaity, S. ;

Natarajan, V. ;

Godbole, S. V. .

JOURNAL OF LUMINESCENCE, 2012, 132 (06) :1329-1338

[6] Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs [J].

Jang, Ho Seong ;

Bin Im, Won ;

Lee, Dong Chin ;

Jeon, Duk Young ;

Kim, Shi Surk .

JOURNAL OF LUMINESCENCE, 2007, 126 (02) :371-377

[7] Luminescence comparison of YAG:Ce phosphors prepared by microwave heating and precipitation methods [J].

Jung, Kyeong Youl ;

Kang, Yun Chan .

PHYSICA B-CONDENSED MATTER, 2010, 405 (06) :1615-1618

[8] Status and future of high-power light-emitting diodes for solid-state lighting [J].

Krames, Michael R. ;

Shchekin, Oleg B. ;

Mueller-Mach, Regina ;

Mueller, Gerd O. ;

Zhou, Ling ;

Harbers, Gerard ;

Craford, M. George .

JOURNAL OF DISPLAY TECHNOLOGY, 2007, 3 (02) :160-175

[9] Monodispersed colloidal spheres for uniform Y2O3:Eu3+ red-phosphor particles and greatly enhanced luminescence by simultaneous Gd3+ doping [J].

Li, Ji-Guang ;

Li, Xiaodong ;

Sun, Xudong ;

Ishigaki, Takamasa .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (31) :11707-11716

[10] Synthesis and luminescent properties of Ln3+ (Eu3+, Sm3+, Dy3+)-doped lanthanum aluminum germanate LaAlGe2O7 phosphors [J].

Li, Yu-Chun ;

Chang, Yen-Hwei ;

Lin, Yu-Feng ;

Chang, Yee-Shin ;

Lin, Yi-Jing .

JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 439 (1-2) :367-375

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