Local structure engineering for active sites in fuel cell electrocatalysts

被引：15
作者：
Cheng, Han [1 ]
Gui, Renjie [1 ]
Liu, Si [1 ]
Xie, Yi [1 ,2 ]
Wu, Changzheng [1 ,2 ]
机构：
[1] Univ Sci & Technol China, CAS Key Lab Mech Behav & Design Mat, Collaborat Innovat Ctr Chem Energy Mat iChEM, Hefei Natl Lab Phys Sci Microscale,CAS Ctr Excel, Hefei 230026, Peoples R China
[2] Hefei Comprehens Natl Sci Ctr, Inst Energy, Hefei 230026, Peoples R China
来源：
SCIENCE CHINA-CHEMISTRY | 2020年 / 63卷 / 11期
基金：
中国国家自然科学基金;
关键词：
local structure engineering; proton exchange membrane fuel cells; oxygen reduction reaction; active sites; OXYGEN REDUCTION REACTION; PROTON-EXCHANGE MEMBRANE; FE-N-C; DENSITY-FUNCTIONAL-THEORY; NITROGEN-DOPED CARBON; HIGH-SURFACE-AREA; ENERGY-CONVERSION; CATALYTIC-ACTIVITY; ELECTRIC VEHICLES; CATHODE CATALYSTS;
D O I：
10.1007/s11426-020-9828-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this review, we surveyed the significance of local structure engineering on electrocatalysts and electrodes for the performance of oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs). Both on precious metal catalysts (PMC) and non-precious metal catalysts (NPMC), the main methods to modulate local structure of active sites have been summarized. By change of atomic coordination, modulation of bonding distortion and synergy effect from hierarchical structure, local structure engineering has influence on the intrinsic activity and stability of electrocatalysts. Moreover, we emphasized the intimate correlation between lyophobicity of electrocatalysts and membrane electrodes by local structure engineering. Our review aimed to inspire the exploration of advanced electrocatalysts and mechanism study for PEMFCs based on local structure engineering.
引用
收藏
页码：1543 / 1556
页数：14
相关论文
共 150 条
[1]   Expert assessments of the cost of light water small modular reactors [J].
Abdulla, Ahmed ;
Azevedo, Ines Lima ;
Morgan, M. Granger .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2013, 110 (24) :9686-9691
[2]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[3]   Oxygen reduction reaction in acid medium at iron phthalocyanine dispersed on high surface area carbon substrate:: tolerance to methanol, stability and kinetics [J].
Baranton, S ;
Coutanceau, C ;
Roux, C ;
Hahn, F ;
Léger, JM .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2005, 577 (02) :223-234
[4]   Non-Pt catalyst as oxygen reduction reaction in microbial fuel cells: A review [J].
Ben Liew, Kien ;
Daud, Wan Ramli Wan ;
Ghasemi, Mostafa ;
Leong, Jun Xing ;
Lim, Wee Su ;
Ismail, Manal .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (10) :4870-4883
[5]   Nanostructured Pt-alloy electrocatalysts for PEM fuel cell oxygen reduction reaction [J].
Bing, Yonghong ;
Liu, Hansan ;
Zhang, Lei ;
Ghosh, Dave ;
Zhang, Jiujun .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (06) :2184-2202
[6]   Theoretical and Experimental Insights into the Origin of the Catalytic Activity of Subnanometric Gold Clusters: Attempts to Predict Reactivity with Clusters and Nanoparticles of Gold [J].
Boronat, Mercedes ;
Leyva-Perez, Antonio ;
Corma, Avelino .
ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (03) :834-844
[7]   The energy divide: Integrating energy transitions, regional inequalities and poverty trends in the European Union [J].
Bouzarovski, Stefan ;
Tirado Herrero, Sergio .
EUROPEAN URBAN AND REGIONAL STUDIES, 2017, 24 (01) :69-86
[8]   Low and non-platinum electrocatalysts for PEMFCs: Current status, challenges and prospects [J].
Brouzgou, A. ;
Song, S. Q. ;
Tsiakaras, P. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 127 :371-388
[9]   Metallic Clusters: Theoretical Background, Properties and Synthesis in Microemulsions [J].
Buceta, David ;
Pineiro, Yolanda ;
Vazquez-Vazquez, Carlos ;
Rivas, Jose ;
Arturo Lopez-Quintela, Manuel .
CATALYSTS, 2014, 4 (04) :356-374
[10]   Finding optimal surface sites on heterogeneous catalysts by counting nearest neighbors [J].
Calle-Vallejo, Federico ;
Tymoczko, Jakub ;
Colic, Viktor ;
Vu, Quang Huy ;
Pohl, Marcus D. ;
Morgenstern, Karina ;
Loffreda, David ;
Sautet, Philippe ;
Schuhmann, Wolfgang ;
Bandarenka, Aliaksandr S. .
SCIENCE, 2015, 350 (6257) :185-189
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