A new Cu-Hf-Al ternary bulk metallic glass with high glass forming ability and ductility

被引:93
作者
Jia, P
Guo, H
Li, Y
Xu, J
Ma, E
机构
[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
[2] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117675, Singapore
[3] Johns Hopkins Univ, Dept Mat Sci & Engn, Baltimore, MD 21218 USA
基金
中国国家自然科学基金;
关键词
metallic glasses; bulk amorphous alloys; glass-forming ability; copper; plasticity; ductility;
D O I
10.1016/j.scriptamat.2006.02.042
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We have discovered a new Cu-based bulk metallic glass (BMG). Although of a simple Cu49Hf42Al9 ternary composition, the as-cast alloy is a monolithic, uniform BMG with a critical diameter as large as 10 mm. The width of the supercooled liquid region AT, and the reduced glass transition temperature T-rg for this glass are 85 K and 0.62, respectively. In addition to its high glass-forming ability and high density of similar to 11 g/cc, this BMG exhibits high ductility with a compressive plastic strain of 11-13%, making it a good candidate for applications as well as for studies of deformation behavior of Cu-based BMGs. (c) 2006 Published by Elsevier Ltd. on behalf of Acta Materialia Inc.
引用
收藏
页码:2165 / 2168
页数:4
相关论文
共 26 条
[1]   A new centimeter-diameter Cu-based bulk metallic glass [J].
Dai, CL ;
Guo, H ;
Shen, Y ;
Li, Y ;
Ma, E ;
Xu, J .
SCRIPTA MATERIALIA, 2006, 54 (07) :1403-1408
[2]   Work-hardenable ductile bulk metallic glass [J].
Das, J ;
Tang, MB ;
Kim, KB ;
Theissmann, R ;
Baier, F ;
Wang, WH ;
Eckert, J .
PHYSICAL REVIEW LETTERS, 2005, 94 (20)
[3]   High copper content bulk glass formation in bimetallic Cu-Hf system [J].
Duan, G ;
Xu, DH ;
Johnson, WL .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2005, 36A (02) :455-458
[4]   Unusual room-temperature compressive plasticity in nanocrystal-toughened bulk copper-zirconium glass [J].
Inoue, A ;
Zhang, W ;
Tsurui, T ;
Yavari, AR ;
Greer, AL .
PHILOSOPHICAL MAGAZINE LETTERS, 2005, 85 (05) :221-229
[5]   Formation, thermal stability and mechanical properties of Cu-Zr and Cu-Hf binary glassy alloy rods [J].
Inoue, A ;
Zhang, W .
MATERIALS TRANSACTIONS, 2004, 45 (02) :584-587
[6]   Formation and mechanical properties of Cu-Hf-Al bulk glassy alloys with a large supercooled liquid region of over 90 K [J].
Inoue, A ;
Zhang, W .
JOURNAL OF MATERIALS RESEARCH, 2003, 18 (06) :1435-1440
[7]   Formation and mechanical properties of Cu-Hf-Ti bulk glassy alloys [J].
Inoue, A ;
Zhang, W ;
Zhang, T ;
Kurosaka, K .
JOURNAL OF MATERIALS RESEARCH, 2001, 16 (10) :2836-2844
[8]   High-strength Cu-based bulk glassy alloys in Cu-Zr-Ti and Cu-Hf-Ti ternary systems [J].
Inoue, A ;
Zhang, W ;
Zhang, T ;
Kurosaka, K .
ACTA MATERIALIA, 2001, 49 (14) :2645-2652
[9]   High-strength Cu-based bulk glassy alloys in Cu-Zr-Ti-Be system [J].
Inoue, A ;
Zhang, T ;
Kurosaka, K ;
Zhang, W .
MATERIALS TRANSACTIONS, 2001, 42 (08) :1800-1804
[10]   A universal criterion for plastic yielding of metallic glasses with a (T/Tg)2/3 temperature dependence -: art. no. 195501 [J].
Johnson, WL ;
Samwer, K .
PHYSICAL REVIEW LETTERS, 2005, 95 (19)