Functionalization of QDs with epoxy group and its transparent and luminescent epoxy matrix nanocomposites for white LED encapsulating material

被引:12
作者
Chen, Lanlan [1 ]
Zhang, Chen [1 ]
Du, Zhongjie [1 ]
Li, Hangquan [1 ]
Zou, Wei [1 ]
机构
[1] Beijing Univ Chem Technol, Key Lab Carbon Fiber & Funct Polymers, Minist Educ, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
Epoxy; Interfaces; Nanocomposites; Optical materials and properties; Quantum dots; ZNO QUANTUM DOTS; OPTICAL-PROPERTIES; NANOPARTICLES; COLOR;
D O I
10.1016/j.matlet.2013.08.024
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A facile approach for synthesizing transparent and luminescent nanocomposites had been carried out by introducing epoxy group functionalized oleic acid (C-18-epoxy) at the interface. The C-18-epoxy could self-assemble with carbon chain of ligand and formed epoxy group functionalized QDs (QDs@epoxy). Therefore, QDs@epoxy had similar polar with epoxy matrix, and could homogenously disperse in nanocomposites. Compared with original ones, QDs@epoxy/epoxy nanocomposites exhibited almost four times transparence and twice luminescence. Furthermore, color rendering index, correlated color temperature and (x, y) of white LED, which was fabricated by nanocomposites (yellow light emitting) encapsulated InGaN chip, were 65, 5260 K and (x=0.3381, y=0.3459), respectively. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:208 / 211
页数:4
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