Pore geometry of sandstone derived from pulsed field gradient NMR

Several parameters of pore geometry are needed for estimating permeability which is a key parameter for the characterization of reservoir sandstones. Powerful techniques for probing the pore space are the self-diffusion and the relaxation time NMR methods. However, the quality of results depends on the petrophysical model which underlies the interpretation of measurements. We applied the pulsed field gradient nuclear magnetic resonance (PFG-NMR) technique and measured time-dependent self-diffusion coefficients, D(A), of water in anhydrite cemented sandstones with low porosity and high tortuosity. The conventional method of fitting data with a function (Pade approximation) of the surface-to-volume ratio and the tortuosity yielded uncertain results. As part of a novel approach, we developed a numerical simulation code based on physical principles and a fractal pore space model. We compared our method with the Pade approximation and tested with data from the literature. For porous media with low toruosity values and simple geometry such as randomly packed glass beads, both methods are in good agreement and give similar results. In sedimentary rocks, however, the new method of calculation is able to determine more accurate details of the pore geometry. However, its main advantage occurs in porous media with fractal geometry or with constricted pores, where the D(Delta)/D-0 curves deviate from the characteristic shape that is found for randomly packed glass beads. (c) 2005 Elsevier B.V. All rights reserved.