Synthesis and Crystal Structure of N-((6-chloropyridin-3-yl)methyl)-6-ethoxy-N-ethyl-3-nitropyridin-2-amine

被引：0

作者：

Wu Dao-Xin ^{[2
]}

Liu Min-Hua ^{[1
,2
]}

Liu Ai-Ping ^{[1
]}

Huang Ming-Zhi ^{[1
]}

Hu Zhi-Bin ^{[1
,3
]}

Ren Ye-Guo ^{[1
]}

Liu Xing-Ping ^{[1
]}

Tang Ming ^{[1
,2
]}

Zuo Wen-Qing ^{[1
,2
]}

机构：

[1] Hunan Res Inst Chem Ind, Natl Engn Res Ctr Agrochem, Changsha 410007, Hunan, Peoples R China

[2] Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410076, Hunan, Peoples R China

[3] Xiangtan Univ, Coll Chem Engn, Xiangtan 411105, Hunan, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2012年 / 31卷 / 05期

关键词：

synthesis; crystal structure; N-((6-chloropyridin-3-yl)methyl)-6-ethoxy-N-ethyl-3-nitropyridin-2-amine; insecticidal and fungicidal activities;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound N-((6-chloropyridin-3-yl)methyl)-6-ethoxy-N-ethyl-3-nitropyridin-2-amine (4) was synthesized by reacting the mixture of 6-chloro-2-ethoxy-3-nitropyridine (1) and 2-chloro-6-ethoxy-3-nitropyridine (2) with 3, and its structure was determined by X-ray single-crystal diffraction. The crystal belongs to the monoclinic system, space group P2(1)/n with a = 7.3441(2), b = 9.9041(3), c = 11.7368 (3) angstrom, alpha = 101.410(2), beta = 102.1340(10), gamma = 99.594(2)degrees, mu = 0.260 mm(-1), M-r = 336.78, V = 798.58(4) angstrom(3), Z = 2, D-c = 1.401g/cm(3), F(000) = 352, T = 296 (2) K, R = 0.0210 and wR = 0.1053.

引用

页码：621 / 624

页数：4

共 7 条

[1]

[Anonymous], MOL CRYSTAL STRUCTUR

[2]

*BURK AN XRAY SYST, 1998, SMART 5 0 SAINT 4 0

[3]

Loso MR, 2007, WO Patent, Patent No. [2007095229, WO2007095229A2]

[4]

Sheldrick G.M., 1997, Programs for Crystal Structure Analysis (Release 97-2)

[5]

Sheldrick G. M., 1997, SHELXL-97, Programs for Crystal Structure Analysis

[6]

Takeo W., 2003, PEST MANAG SCI, V59, P1016

[7]

Zhang Y B., 2010, WORLD PESTICIDES, V32, P54

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