Iron-Catalysed Markovnikov Hydrothiolation of Styrenes

被引：62

作者：

Cabrero-Antonino, Jose R. ^{[1
]}

Leyva-Perez, Antonio ^{[1
]}

Corma, Avelino ^{[1
]}

机构：

[1] Univ Politecn Valencia, Inst Tecnol Quim UPV CSIC, Consejo Super Invest Cient, Valencia 46022, Spain

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 04期

关键词：

benzylic thioethers; bis(triflimide)- iron(III); hydrothiolation; iron catalysis; Markovnikov addition; styrenes; ALKYL PHENYL SULFIDES; CONJUGATE ADDITION; EFFICIENT SYNTHESIS; ALPHA-OLEFINS; H BONDS; C-C; THIOLS; ACID; TRANSFORMATION; COMPLEXES;

D O I：

10.1002/adsc.201100731

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The bis(triflimide)iron(III) salt catalyzes the hydrothiolation of styrenes in a Markovnikov fashion with good selectivities and high yields. After isolation, different benzylic thioethers are obtained. This iron(III) catalyst is unique in terms of regioselectivity and represents a sustainable and economic alternative to those processes based on stoichiometric reagents.

引用

页码：678 / 687

页数：10

共 71 条

[51] STEREOSPECIFIC NUCLEOPHILIC-ADDITION REACTIONS TO OLEFINS - ADDITION OF THIOLS TO ALPHA,BETA-UNSATURATED CARBOXYLIC-ACID DERIVATIVES [J].