Ba0.85Ca0.15Ti0.90Zr0.10O3 Lead-free Ceramics with a Sintering Aid of MnO

被引：9

作者：

Wu, Jiagang ^{[1
]}

Wang, Zhuo ^{[1
]}

Zhang, Binyu ^{[1
]}

Zhu, Jianguo ^{[1
]}

Xiao, Dingquan ^{[1
]}

机构：

[1] Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China

来源：

INTEGRATED FERROELECTRICS | 2013年 / 141卷 / 01期

基金：

中国国家自然科学基金;

关键词：

(Ba; Ca)(Ti; Zr)O-3; MnO; Microstructure; Electrical Properties; BARIUM-TITANATE CERAMICS; PIEZOELECTRIC PROPERTIES; TEMPERATURE-DEPENDENCE; BATIO3; CERAMICS; POINT; ABSORPTION; CONSTANTS; CRYSTALS; STRAIN;

D O I：

10.1080/10584587.2013.778757

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

Effects of MnO on the microstructure and electrical properties of Ba0.85Ca0.15Ti0.90 Zr0.10O3 (BCTZ) ceramics were investigated. Its sintering temperature decreases, a phase boundary shifts to a higher temperature, and a denser microstructure is induced by introducing MnO. Double P-E loops were observed in BCTZ with x 0.30wt% MnO due to the involvement of more defects. Piezoelectric properties are degraded by doping MnO, but the temperature stability of piezoelectric properties is improved with a low dielectric loss of approximate to 0.63%. As a result, BCTZ ceramics with x = 0.15wt% MnO have optimum electrical properties: d(33) approximate to 382 pC/N, k(p) approximate to 44.5%, E-r approximate to 2611, and tan approximate to 0.63%.

引用

页码：89 / 98

页数：10

共 32 条

[1] [Anonymous], J APPL PHYS
[2] POINT DEFECTS AND SINTERING OF LEAD ZIRCONATE-TITANATE
ATKIN, RB
FULRATH, RM
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1971, 54 (05) : 265 - &
[3] Thermo-Raman and dielectric constant studies of CaXBa1-XTiO3 ceramics
Baskaran, N
Chang, H
[J]. MATERIALS CHEMISTRY AND PHYSICS, 2003, 77 (03) : 889 - 894
[4] ELASTIC, PIEZOELECTRIC, AND DIELECTRIC CONSTANTS OF POLARIZED BARIUM TITANATE CERAMICS AND SOME APPLICATIONS OF THE PIEZOELECTRIC EQUATIONS
BECHMANN, R
[J]. JOURNAL OF THE ACOUSTICAL SOCIETY OF AMERICA, 1956, 28 (03) : 347 - 350
[5] Begg BD, 1996, J AM CERAM SOC, V79, P2666, DOI 10.1111/j.1151-2916.1996.tb09032.x
[6] Characterization of Ba(Zr0.2Ti0.8)O3 thin films deposited by RF-magnetron sputtering
Choi, WS
Jang, BS
Lim, DG
Yi, J
Hong, B
[J]. JOURNAL OF CRYSTAL GROWTH, 2002, 237 : 438 - 442
[7] Aging effect and large recoverable electrostrain in Mn-doped KNbO3-based ferroelectrics
Feng, Zuyong
Ren, Xiaobing
[J]. APPLIED PHYSICS LETTERS, 2007, 91 (03)
[8] Effects of CuO on the Electrical Properties of CaTiO3-Modified [(Na0.52K0.48)0.955Li0.045](Nb0.955Sb0.045)O3 Lead-Free Piezoceramics
Huang, Xiaolei
Xiao, Dingquan
Li, Xuhai
Wu, Wenjuan
Liang, Wenfeng
Xie, Ruishi
Zhu, Jianguo
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2010, 93 (09) : 2563 - 2566
[9] Dielectric and piezoelectric properties of Mn-doped Na0.5K0.5NbO3 Single crystals grown by flux method
Inagaki, Yumi
Kakimoto, Ken-ichi
[J]. APPLIED PHYSICS EXPRESS, 2008, 1 (06) : 0616021 - 0616023
[10] Double hysteresis loops induced by Mn doping in Pb0.99Nb0.02(Zr0.95Ti0.05)0.98O3 ferroelectric ceramics
Jiang, Meng
Li, Xuhai
Zhu, Jiliang
Zhu, Xiaohong
Shi, Wei
Li, Lihua
Xiao, Dingquan
Zhu, Jianguo
[J]. CURRENT APPLIED PHYSICS, 2010, 10 (02) : 526 - 530

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