The Methods and Stands for Testing Fixed Sorbent and Sorbent Polymer Composite Materials for the Removal of Mercury from Flue Gases

被引:4
作者
Gorecki, Jerzy [1 ]
Macherzynski, Mariusz [1 ]
Chmielowiec, Jacek [2 ]
Borovec, Karel [3 ]
Waleka, Mateusz [4 ]
Deng, Yinyou [4 ]
Sarbinowski, Janusz [5 ]
Pasciak, Grzegorz [2 ]
机构
[1] Univ Sci & Technol Krakow, Fac Energy & Fuels, Dept Coal Chem & Environm Sci, AGH, al A Mickiewicza 30, PL-30059 Krakow, Poland
[2] Polish Acad Sci, Inst Low Temp & Struct Res, Okolna 2, PL-50422 Wroclaw, Poland
[3] Tech Univ Ostrava, Energy Res Ctr VSB, 17 Listopadu 15-2172, Ostrava 70833, Czech Republic
[4] Univ Sci & Technol Krakow, Doctoral Sch, AGH, al A Mickiewicza 30, PL-30059 Krakow, Poland
[5] INBRAS, ul Transportowca 13, PL-88100 Inowroclaw, Poland
关键词
mercury; flue gas; sorbent polymer composite; fixed sorbent materials; coal; cleaning technology; ELEMENTAL MERCURY; DESULFURIZATION; NANOPARTICLES; SPECIATION; OXIDATION; ZEOLITES;
D O I
10.3390/en15238891
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The most common methods of reducing mercury emissions are the use of fixed bed granular sorbents and sorbent injection. However, both of these methods have disadvantages, such as increasing the flow resistance or the need to remove the sorbent from flue gas, respectively. These disadvantages can be eliminated by using sorbents permanently bound to construction materials (fixed sorbent materials-FSMs) or mixed with construction materials (sorbent polymer composites-SPCs). The approach is unique in the world literature as well as the development of three stands and procedures enabling the testing of FSMs or SPC materials based on Tarflen as a construction material. In order to further tests of FSMs and SPCs, the system for laboratory tests and two systems for industrial tests are developed. These stands and procedures enable determination of the influence of: FSM or SPC module shapes, flue gas properties (e.g., composition, temperature, flow rate), and mercury concentration on the effectiveness of mercury removal by SPCs and FSMs. In this paper, the influence of module shapes, gas velocity, and temperature is particularly considered. In the final industrial tests, the FSM removes 99.5% Hg after 42 days and the SPC removes from 99.5% to 82.3% after 34 days.
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页数:18
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