Solvent extraction of lanthanides into an ionic liquid containing N,N,N′,N′-tetrakis(2-pyridylmethyl)ethylenediamine

被引:28
作者
Shimojo, Kojiro [1 ]
Naganawa, Hirochika
Kubota, Fukiko
Goto, Masahiro
机构
[1] Japan Atom Energy Agcy, Nucl Sci & Engn Directorate, Div Environm & Radiat Sci, Tokai, Ibaraki 3191195, Japan
[2] Kyushu Univ, Grad Sch Engn, Dept Appl Chem, Fukuoka 8190395, Japan
[3] Kyushu Univ, Ctr Future Chem, Fukuoka 8190395, Japan
关键词
D O I
10.1246/cl.2006.484
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The extraction behavior of lanthanides from aqueous solutions into an ionic liquid (IL) was investigated with N,N,N',N'-tetrakis(2-pyridylmethyl)ethylenediamine (TPEN) as a ligand. The extraction performance of TPEN for lanthanides is greatly enhanced by dissolution in IL compared to in chloroform. Furthermore, the stripping of lanthanides from IL into a receiving phase is successfully achieved under acidic conditions.
引用
收藏
页码:484 / 485
页数:2
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