Control the Entire Journey of Pesticide Application on Superhydrophobic Plant Surface by Dynamic Covalent Trimeric Surfactant Coacervation

被引：137

作者：

Liu, Bin ^{[1
,2
]}

Fan, Yaxun ^{[1
,2
]}

Li, Haofei ^{[1
,2
]}

Zhao, Weiwei ^{[1
,2
]}

Luo, Siqi ^{[1
,2
]}

Wang, Hua ^{[1
,2
]}

Guan, Bo ^{[1
,2
]}

Li, Qiaolian ^{[1
,2
]}

Yue, Jiling ^{[1
,2
]}

Dong, Zhichao ^{[3
,4
]}

Wang, Yilin ^{[1
,2
]}

Jiang, Lei ^{[3
,4
]}

机构：

[1] Chinese Acad Sci, CAS Key Lab Colloid Interface & Chem Thermodynam, CAS Res Educ Ctr Excellence Mol Sci, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

[3] Chinese Acad Sci, Tech Inst Phys & Chem, CAS Key Lab Bioinspired Mat & Interfacial Sci, Beijing 100190, Peoples R China

[4] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

ADVANCED FUNCTIONAL MATERIALS | 2021年 / 31卷 / 05期

基金：

美国国家科学基金会;

关键词：

coacervation; deposition; dynamic covalent; superhydrophobic surfaces; sustainable agriculture; DROP IMPACT; MICROCAPSULES; CHALLENGES; RESISTANCE; VESICLES;

D O I：

10.1002/adfm.202006606

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Vast wastage of pesticides has caused significant environmental pollution and economic loss, which occurs in any step during the entire process of pesticide application. However, the existing strategies for controlling pesticide losses are step specific. Here, a comprehensive strategy to substantively improve pesticide efficiency on the basis of precise designs from beginning to end is developed. A water-based coacervate with synthesized imine-based dynamic covalent trimeric surfactants to synergistically control encapsulation, deposition, retention, and release of pesticides on water-repellent plants is constructed. The coacervate consists of nanosized networks and abundant tightly bonded water, leading to effective encapsulation of hydrophilic/hydrophobic pesticides. Meanwhile, the network-like microstructure entangles with the micro/nanostructures of superhydrophobic surface, ensuring complete deposition on superhydrophobic plant surface after high-speed impact and inhibition of wind/rainwater erosion. Moreover, the CO2-induced degradative surfactant coacervate determines the precise pesticide release. The dynamic coacervate as an innovative pesticide formula provides a prospective way for pesticide application, and is expected to promote productive and sustainable agriculture.

引用

页数：11

共 51 条

[21] Nano-based smart pesticide formulations: Emerging opportunities for agriculture [J].