Interactions of Imidazolium-Based Ionic Liquids with Oxide Surfaces Controlled by Alkyl Chain Functionalization

被引：23

作者：

Schernich, Stefan ^{[1
]}

Laurin, Mathias ^{[1
]}

Lykhach, Yaroslava ^{[1
]}

Tsud, Nataliya ^{[2
]}

Sobota, Marek ^{[1
]}

Skala, Tomas ^{[2
]}

Prince, Kevin C. ^{[3
]}

Taccardi, Nicola ^{[4
,5
]}

Wagner, Valentin ^{[4
,5
]}

Steinrueck, Hans-Peter ^{[1
]}

Matolin, Vladimir ^{[2
]}

Wasserscheid, Peter ^{[4
,5
]}

Libuda, Joerg ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Lehrstuhl Phys Chem 2, D-91058 Erlangen, Germany

[2] Charles Univ Prague, Fac Math & Phys, Dept Surface & Plasma Sci, CR-18000 Prague 8, Czech Republic

[3] Sincrotrone Trieste SCpA, I-34149 Basovizza Trieste, Italy

[4] Univ Erlangen Nurnberg, Lehrstuhl Chem Reakt Tech, D-91058 Erlangen, Germany

[5] Univ Erlangen Nurnberg, Erlangen Catalysis Resource Ctr, D-91058 Erlangen, Germany

来源：

CHEMPHYSCHEM | 2013年 / 14卷 / 16期

关键词：

cerium oxide; IR spectroscopy; photoelectron spectroscopy; surface chemistry; thin films; PHOTOELECTRON-SPECTROSCOPY; METAL-SURFACES; THIN-FILMS; HYDROFORMYLATION; ADSORPTION; CATALYSIS; ULTRATHIN; SCIENCE; GROWTH; STM;

D O I：

10.1002/cphc.201300792

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

From a different angle: Thin films of functionalized ionic liquids are deposited on cerium oxides following a surface science approach. The functionalization of the alkyl chain changes its orientation with respect to the surface plane from normal to parallel. This then leads to a different surface chemistry at higher temperatures. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3673 / 3677

页数：5

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