Photochemical ion receptor based on a structurally distorted ruthenium(II) complex having a crown-ether moiety at the 3,3'-positions on the 2,2'-bipyridine ligand

Ru(bpy)(2)(CE-bpy)(2+) was prepared where bpy and CE-bpy were 2,2'-bipyridine and bpy having a crown-ether moiety at the 3,3'-positions, respectively. Although Ru(bpy)(2)(CE-bpy)(2+) showed only very weak emission in acetonitrile, recognition of Na+, Li+, or K+ by the crown-ether moiety in CE-bpy resulted in increases in both the emission intensity and the lifetime of the complex, demonstrating that it acted as a photoreceptor. The results were discussed in terms of a steric hindrance between the 3,3'-substituents on CE-bpy and structural changes in both CE-bpy and the complex upon ion recognition, as studied by variable-temperature H-1-NMR and steady-state/dynamic emission spectroscopy of the complex.