Issues in the synthesis of crystalline molecular sieves: Towards the crystallization of low framework-density structures

被引:243
作者
Corma, A
Davis, ME
机构
[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia, Spain
[2] CALTECH, Pasadena, CA 91125 USA
基金
欧盟地平线“2020”;
关键词
crystal engineering; mesoporous materials; molecular sieves; zeolites;
D O I
10.1002/cphc.200300997
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fundamental and practical interest in crystalline, microporous, molecular sieves is largely a direct consequence of the fact that their bulk properties can be manipulated through variations in atomic structure. This correspondence between the macroscale and the atomic scale is due to the uniformity of these crystalline materials. Control of the atomic structure therefore is of extreme importance, and is the thesis of this Review. Synthesis mechanisms and the parameters that can direct the crystal assembly pathway and the ultimate product formed are discussed and rationalized.
引用
收藏
页码:304 / 313
页数:10
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