Novel Porous Chitosan Resin for the Removal of Cd(II) from Aqueous Solutions

被引:1
作者
Cang, Hui [1 ]
Lu, Yu [1 ]
Xu, Qi [1 ]
机构
[1] Yancheng Inst Technol, Coll Chem Engn & Biol, Yancheng 224051, Peoples R China
关键词
Chitosan; Resin; Cadmium; Removal; CHELATING RESIN;
D O I
10.14233/ajchem.2013.14402
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel chitosan derivative, porous tetraethylenepentamine-type chitosan resin, was chemically modified by chloromethyloxirane and tetraethylenepentamine. The uptake behaviour of resin towards Cd(II) was studied in aqueous medium, where the maximum adsorption capacity of the resin was 125.1 mg/g at pH 8.0 at room temperature. Kinetic studies referred that the uptake reaction is pseudo second order. The uptake reaction is a monolayer and found to be endothermic. Interference of other cations and anions in Cd(II) adsorption was found to be significant. The resin was regenerated effectively (desorption ratio approximate to 98 %) using a mixture of 2 M NaCl and 0.5 M and can be regenerated many times as well as stable performance in adsorption of Cd(II).
引用
收藏
页码:6647 / 6651
页数:5
相关论文
共 13 条
[1]   Copper [J].
Barceloux, DG .
JOURNAL OF TOXICOLOGY-CLINICAL TOXICOLOGY, 1999, 37 (02) :217-230
[2]  
CHEREMISINOFF PN, 1993, CARBON ADSORPTION PO
[3]   Efficient removal of Hg(II) using magnetic chelating resin derived from copolymerization of bisthiourea/thiourea/glutaraldehyde [J].
Donia, Ahmed M. ;
Atia, Asem A. ;
Heniesh, Amr M. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2008, 60 (01) :46-53
[4]  
EPA (US Environmental Protection Agency) Office of Solid Waste draft PBT Chemical List, 1998, EPA530D98001A OFF SO
[5]  
Ho Y.S., 1997, P 4 CHIN JAP US S AD
[6]   High-capacity chitosan-based chelating resin for on-line collection of transition and rare-earth metals prior to inductively coupled plasma-atomic emission spectrometry measurement [J].
Katarina, Rosi Ketrin ;
Oshima, Mitsuko ;
Motomizu, Shoji .
TALANTA, 2009, 79 (05) :1252-1259
[7]  
Ngah WSW, 1998, J APPL POLYM SCI, V69, P2305, DOI 10.1002/(SICI)1097-4628(19980919)69:12<2305::AID-APP1>3.0.CO
[8]  
2-C
[9]   Chitosan selectivity for removing cadmium (II), copper (II), and lead (II) from aqueous phase: pH and organic matter effect [J].
Rangel-Mendez, J. R. ;
Monroy-Zepeda, R. ;
Leyva-Ramos, E. ;
Diaz-Flores, P. E. ;
Shirai, K. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 162 (01) :503-511
[10]   Sequential-injection on-line preconcentration using chitosan resin functionalized with 2-amino-5-hydroxy benzoic acid for the determination of trace elements in environmental water samples by inductively coupled plasma-atomic emission spectrometry [J].
Sabarudin, Akhmad ;
Lenghor, Narong ;
Oshima, Mitsuko ;
Hakim, Lukman ;
Takayanagi, Toshio ;
Gao, Yun-Hua ;
Motomizu, Shoji .
TALANTA, 2007, 72 (05) :1609-1617