Terephthalate Derivatives as Links in the Construction of Two Novel Cd(II) Coordination Polymers

被引：3

作者：

Rong Zhong-Hua ^{[1
,2
]}

Ma Yun-Sheng ^{[2
]}

Tang Xiao-Yan ^{[2
]}

Yuan Rong-Xin ^{[2
]}

Xie Ji-Min ^{[1
]}

机构：

[1] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China

[2] Changshu Inst Technol, Jiangsu Key Lab Adv Funct Mat, Sch Chem & Mat Engn, Changshu 215500, Jiangsu, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 29卷 / 06期

关键词：

coordination polymer; crystal structure; cadmium; terephthalic acid; METAL-ORGANIC FRAMEWORKS; DESIGN;

D O I：

10.3969/j.issn.1001-4861.2013.00.189

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel cadmium coordination polymers: Cd(BrBDC)(py) (1) and Cd(NH2BDC)(H2O) (2) (BrBDC=2-bromo-1,4-benzenedicarboxylate, NH2BDC =2-amino-1,4-benzenedicarboxylate, py =pyridine), were synthesized under solvothermal conditions. The crystal structure of Cd(BrBDC)(py) is based on infinite chains of carboxylato-bridged six coordinated Cd(II) ions that are linked via the BrBDC ligands to form a 2D structure. Cd(NH2BDC) (H2O) is based on brick-like 2D layers constructed by carboxylato that are crosslinked by the amino groups into a 3D structure. The photoluminescence of both compounds are studied. CCDC: 915674, 1; 915673, 2.

引用

页码：1249 / 1254

页数：6

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