Strong two-photon absorption enhancement in a unique bis-porphyrin bearing a diketopyrrolopyrrole unit

被引：60
作者：
Nowak-Krol, Agnieszka [1 ]
Grzybowski, Marek [1 ]
Romiszewski, Jerzy [2 ]
Drobizhev, Mikhail [3 ]
Wicks, Geoffrey [3 ]
Chotkowski, Maciej [2 ]
Rebane, Aleksander [3 ,4 ]
Gorecka, Ewa [2 ]
Gryko, Daniel T. [1 ]
机构：
[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland
[2] Warsaw Univ, Fac Chem, PL-00273 Warsaw, Poland
[3] Montana State Univ, Dept Phys, Bozeman, MT 59717 USA
[4] NICPB, EE-12618 Tallinn, Estonia
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 75期
关键词：
NONLINEAR-OPTICAL PROPERTIES; C-H ACTIVATION; RESONANCE ENHANCEMENT; EXCITATION; DIMERS; OLIGOMERS; STATE;
D O I：
10.1039/c3cc44728f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A pi-extended bis-porphyrin bridged via a diketopyrrolopyrrole unit was prepared in 5 steps. This fully conjugated pi-system displays strongly distorted linear absorption, while its two-photon absorption cross-section reaches 2500-3000 GM at 940 nm. LC-like behaviour, easy orientation and low viscosity are, according to XRD, POM and DSC measurements, due to formation of plastic rather than a liquid crystal.
引用
收藏
页码：8368 / 8370
页数：3
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