Reversible, Complete Cleavage of Si=Si Double Bonds by Isocyanide Insertion

被引：38
作者：
Majumdar, Moumita [1 ]
Huch, Volker [1 ]
Bejan, Iulia [1 ]
Meltzer, Antje [1 ]
Scheschkewitz, David [1 ]
机构：
[1] Univ Saarland, Krupp Lehrstuhl Allgemeine & Anorgan Chem, D-66125 Saarbrucken, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 12期
基金：
英国工程与自然科学研究理事会;
关键词：
disilenes; insertion reactions; isocyanides; reversibility; silenes; CHEMICAL-SHIFTS; SILICON; DISILENE; SILENES; CYCLOADDITION; CHEMISTRY; SILYLENE; ANALOGS; ALKENES;
D O I：
10.1002/anie.201209281
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
There and back: An isocyanide-centered silene-disilene reversibility was observed for the insertion of isocyanides into unsymmetrically substituted disilenes. This reaction leads to the formation of silenes at room temperature; the disilene is regenerated in the presence of a Lewis acid. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：3516 / 3520
页数：5
相关论文
共 60 条
  • [1] Synthesis, structure, and bonding of stable dialkylsilaketenimines
    Abe, T
    Iwamoto, T
    Kabuto, C
    Kira, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (13) : 4228 - 4229
  • [2] [Anonymous], 1971, ANGEW CHEM INT ED EN, V10, P409
  • [3] [Anonymous], 2007, ANGEW CHEM INT ED, V46, P3349
  • [4] [Anonymous], 2007, ANGEW CHEM INT ED, V46, P5783
  • [5] [Anonymous], 2012, ANGEW CHEM INT ED, V51, P6785
  • [6] [Anonymous], 2003, ANGEW CHEM INT ED, V42, P1640
  • [7] [Anonymous], 2007, ANGEW CHEM INT ED, V46, P3346
  • [8] [Anonymous], 2002, ANGEW CHEM INT ED, V41, P1402
  • [9] Ayakyan V. G., 2003, J ORGANOMET CHEM, V686, P257
  • [10] PHOTOCHEMICAL REARRANGEMENTS OF STABLE SILENES
    BAINES, KM
    BROOK, AG
    FORD, RR
    LICKISS, PD
    SAXENA, AK
    CHATTERTON, WJ
    SAWYER, JF
    BEHNAM, BA
    [J]. ORGANOMETALLICS, 1989, 8 (03) : 693 - 709
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