Experimental and predicted volumetric and refractive index properties of ternary mixtures of iodoethane with toluene and alcohols at temperature 298.15 K and pressure 101 kPa

被引:20
作者
Atik, Z [1 ]
机构
[1] Univ Sci & Technol, Fac Chem, Algiers 16112, Algeria
关键词
density; refractive index; excess molar volume; change in refractive index; binary mixture; ternary mixture; empirical equation; prediction; iodoethane;
D O I
10.1016/j.jct.2005.05.004
中图分类号
O414.1 [热力学];
学科分类号
摘要
Excess molar volumes V-m(E) and change in refractive indices Delta(mix)n of the binary mixtures of (toluene + methanol), (toluene + ethanol), (toluene + 1-propanol), (toluene + iodoethane), (methanol + iodoethane), (ethanol + iodoethane), (1-propanol + iodoethane), and the ternary mixtures of (toluene + methanol + iodoethatic), (toluene + ethanol + iodoethane), and (toluene + 1-propanol + iodoethane) were measured with vibrating-tube densimeters and an Abbe-type refractometer at the temperature 298.15 K and the pressure 101 kPa. The experimental V-m(E) and Delta(mix)n values of the ternary systems were predicted by empirical equations using binary solution data. (C) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:201 / 208
页数:8
相关论文
共 22 条
[1]  
Acree Jr WE, 1984, THERMODYNAMIC PROPER, P62
[2]   EXCESS-ENTHALPIES OF (A BROMOCHLOROALKANE PLUS TETRACHLOROMETHANE OR BENZENE) AT THE TEMPERATURE 298.15 K [J].
ARTAL, M ;
EMBID, JM ;
OTIN, S ;
VELASCO, I .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1995, 27 (04) :399-403
[3]   EXCESS MOLAR ENTHALPIES OF (FLUOROBENZENE OR TRIFLUOROMETHYLBENZENE OR IODOETHANE PLUS METHANOL OR TOLUENE) AT THE TEMPERATURE 313.15-K AND PRESSURE 0.7 MPA [J].
ATIK, Z ;
MEENTS, B ;
GMEHLING, J .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1993, 25 (07) :905-907
[4]   Densities and excess molar volumes of binary and ternary mixtures of aqueous solutions of 2,2,2-trifluoroethanol with acetone and alcohols at the temperature of 298.15 K and pressure of 101 kPa [J].
Atik, Z .
JOURNAL OF SOLUTION CHEMISTRY, 2004, 33 (11) :1447-1466
[5]  
ATIK Z, 1995, J SOC ALGER CHIM, V5, P81
[7]  
COLINET C, 1967, THESIS U GRENOBLE
[8]   EMPIRICAL-METHODS OF PREDICTING AND REPRESENTING THERMODYNAMIC PROPERTIES OF TERNARY SOLUTION PHASES [J].
HILLERT, M .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1980, 4 (01) :1-12
[9]  
IGLESIAS M, 1995, J CHEM THERMODYN, V7, P253
[10]  
IMENEZ E, 2000, J CHEM ENG DATA, V45, P862