Preparation of Highly Moisture-Resistant Black-Colored Metal Organic Frameworks

被引：168
作者：
Yang, Seung Jae [1 ,2 ]
Park, Chong Rae [1 ,2 ]
机构：
[1] Seoul Natl Univ, Carbon Nanomat Design Lab, Global Res Lab, Res Inst Adv Mat, Seoul 151744, South Korea
[2] Seoul Natl Univ, Dept Mat Sci & Engn, Seoul 151744, South Korea
来源：
ADVANCED MATERIALS | 2012年 / 24卷 / 29期
基金：
新加坡国家研究基金会;
关键词：
HYDROGEN STORAGE CAPACITY; HIGH-SURFACE-AREA; POROUS CARBON; MOF-5; STABILITY; POROSITY;
D O I：
10.1002/adma.201200790
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A straightforward method for significantly improving the moisture resistance of MOFs is described. In the proposed method, MOFs are subjected to thermal treatment, thus inducing the formation of an amorphous carbon coating on the MOF surfaces that prevents hydrolysis. This approach should open up new practical applications for MOFs in areas hitherto unexplored due to concerns regarding moisture sensitivity. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4010 / 4013
页数：4
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