Enhanced Sunlight Photocatalytic Performance of Hafnium Doped ZnO Nanoparticles for Methylene Blue Degradation

被引:14
作者
Ahmad, M. [1 ,2 ,3 ]
Iqbal, Z. [3 ]
Hong, Zhanglian [1 ,2 ]
Yang, Jingxia [1 ,2 ]
Zhang, Yuewei [1 ,2 ]
Khalid, N. R. [1 ,2 ,3 ]
Ahmed, E. [3 ]
机构
[1] Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
[2] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
[3] Bahauddin Zakariya Univ, Dept Phys, Multan 60800, Pakistan
基金
中国博士后科学基金;
关键词
Nanocrystalline ZnO; sol-gel synthesis; Hf-doped ZnO; photocatalysis; SOLVOTHERMAL PREPARATION; NANOSIZED TIO2; PROPERTY; POWDERS;
D O I
10.1080/10584587.2013.788943
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
A series of Hf-doped ZnO nanocatalysts were synthesized by sol-gel method with a doping content up to 6mol%. The structure, morphologies, and optical properties of the synthesized catalysts were characterized by XRD, TEM, FTIR and UV-Vis absorption spectrometer. The photocatalytic activity was evaluated by the Methylene Blue degradation in aqueous solution under sun light irradiation. Irradiation time and doping content had important effects on the photocatalytic activity of Hf-doped ZnO. Hafnium content had an optimum value of 2mol% for achieving high photocatalytic activity. The experiments demonstrated that MB was effectively degraded up to 85% within 120 minutes. It was confirmed that the presence of Hafnium in ZnO catalysts could enhance the photocatalytic oxidation.
引用
收藏
页码:108 / 114
页数:7
相关论文
共 18 条
[1]   High-density phases of ZnO: Structural and compressive parameters [J].
Desgreniers, S .
PHYSICAL REVIEW B, 1998, 58 (21) :14102-14105
[2]   Solvothermal Preparation of Carbon-Enhanced TiO2/Graphene Composite and Its Visible Light Photocatalytic Properties [J].
Hong, Zhanglian ;
Zhang, Yuewei ;
Jiao, Xiaoliang ;
He, Chan ;
Khalid, N. R. ;
Yang, Jingxia .
INTEGRATED FERROELECTRICS, 2012, 138 :152-158
[3]   Synthesis, characterization and photocatalytic property of nanostructured Al-doped ZnO powders prepared by spray pyrolysis [J].
Hsiao, Kuang-Che ;
Liao, Shih-Chieh ;
Chen, Yi-Jia .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2007, 447 (1-2) :71-76
[4]   Synthesis and characterization of nanocrystalline ZnO powders by a novel combustion synthesis method [J].
Hwang, CC ;
Wu, TY .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2004, 111 (2-3) :197-206
[5]   Fabrication, characterization and photocatalytic activity of La-doped ZnO nanowires [J].
Jia, Tiekun ;
Wang, Weimin ;
Long, Fei ;
Fu, Zhengyi ;
Wang, Hao ;
Zhang, Qingjie .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 484 (1-2) :410-415
[6]   Nitrogen doped TiO2 nanoparticles decorated on graphene sheets for photocatalysis applications [J].
Khalid, N. R. ;
Ahmed, E. ;
Hong, Zhanglian ;
Zhang, Yuewei ;
Ahmad, M. .
CURRENT APPLIED PHYSICS, 2012, 12 (06) :1485-1492
[7]   Synergistic effects of Fe and graphene on photocatalytic activity enhancement of TiO2 under visible light [J].
Khalid, N. R. ;
Hong, Zhanglian ;
Ahmed, E. ;
Zhang, Yuewei ;
Chan, He ;
Ahmad, M. .
APPLIED SURFACE SCIENCE, 2012, 258 (15) :5827-5834
[8]  
Kwon YJ, 2002, J CERAM PROCESS RES, V3, P146
[9]   One-step solvothermal preparation of TiO2/C composites and their visible-light photocatalytic activities [J].
Li, Ming ;
Zhou, Shifeng ;
Zhang, Yuewei ;
Chen, Guangqin ;
Hong, Zhanglian .
APPLIED SURFACE SCIENCE, 2008, 254 (13) :3762-3766
[10]   Synergistic effect of two surface complexes in enhancing visible-light photocatalytic activity of titanium dioxide [J].
Li, Ming ;
Hong, Zhanglian ;
Fang, Yanan ;
Huang, Fuqiang .
MATERIALS RESEARCH BULLETIN, 2008, 43 (8-9) :2179-2186