Dynamic Combinatorial Evolution within Self-Replicating Supramolecular Assemblies

被引：143

作者：

Nguyen, Remi ^{[1
]}

Allouche, Lionel ^{[2
]}

Buhler, Eric ^{[3
]}

Giuseppone, Nicolas ^{[1
]}

机构：

[1] Univ Strasbourg, SAMS Lab, icFRC, Inst Charles Sadron,CNRS,UPR 22, F-67034 Strasbourg 2, France

[2] Univ Strasbourg, Inst Chim, Serv RMN, F-67008 Strasbourg, France

[3] Univ Paris 07, Mat & Syst Complexes Lab, UMR 7057, F-75205 Paris 13, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 06期

关键词：

block copolymers; combinatorial chemistry; micelles; self-assembly; self-replication; CHEMISTRY; LIBRARIES; SYSTEMS; LIFE; NETWORKS;

D O I：

10.1002/anie.200804602

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Survival of the fittest: Self-assemblies made of dynamic block copolymers (dynablocks) can self-replicate by catalyzing the formation of their own building blocks. Moreover, in competition experiments, the differential thermodynamic stabilities and autocatalytic efficiencies of these self-assemblies lead to sigmoid growth of the most efficient self-replicator and to depletion of its competitors. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1093 / 1096

页数：4

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