Colloidal Fe-Doped Indium Oxide Nanoparticles: Facile Synthesis, Structural, and Magnetic Properties

被引:106
作者
Singhal, Anshu [1 ]
Achary, S. N. [1 ]
Manjanna, J. [3 ,4 ]
Jayakumar, O. D. [1 ]
Kadam, R. M. [2 ]
Tyagi, A. K. [1 ]
机构
[1] Bhabha Atom Res Ctr, Div Chem, Bombay 400085, Maharashtra, India
[2] Bhabha Atom Res Ctr, Div Radiochem, Bombay 400085, Maharashtra, India
[3] Iwate Univ, Fac Engn, NDE, Morioka, Iwate 0208551, Japan
[4] Iwate Univ, Fac Engn, Ctr Sci Res, Morioka, Iwate 0208551, Japan
关键词
FERROMAGNETISM; EXCHANGE; NANOCRYSTALS; IN2O3; IONS; MN; CO;
D O I
10.1021/jp8097846
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the preparation, characterization, and magnetic properties of highly crystalline colloidal Fe-doped indium oxide nanoparticles. The nanoparticles have been prepared in high yields by simple one-pot thermal decomposition of indium and iron precursors in hexadecylamine and can be easily dispersed in solvents like chloroform and toluene. Detailed X-ray diffraction, microstructure, and Raman studies reveal that the nanoparticles are single phase cubic bixbyite structure without any parasitic secondary phases. DC magnetization studies as a function of temperature and field indicate that nanoparticles are weakly ferromagnetic at room temperature (RT). This observation is further confirmed by the electron paramagnetic resonance spectra of the samples, which show a distinct ferromagnetic resonance signal at RT.
引用
收藏
页码:3600 / 3606
页数:7
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