Metallophthalocyanines catalyzed cyclopropanation of olefins with trimethylsilyldiazomethane: A facile and stereoselective synthesis of silylcyclopropanes

被引：22

作者：

Sharma, Vishal B. ^{[1
]}

Jain, Suman L. ^{[1
]}

Sain, Bir ^{[1
]}

机构：

[1] Indian Inst Petr, Chem & Biotechnol Div, Dehra Dun 248005, Uttar Pradesh, India

来源：

CATALYSIS COMMUNICATIONS | 2006年 / 7卷 / 07期

关键词：

silylcyclopropanes; metallophthalocyanines; trimethylsilyldiazomethane; cyclopropanation; olefin;

D O I：

10.1016/j.catcom.2005.12.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Metallophthalocyanines were found to be potent and versatile catalysts for the stereoselective synthesis of C-silyl cyclopropanes with high trans-selectivity by the reaction of olefins with trimethylsilyldiazomethane. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：454 / 456

页数：3

共 23 条

[1] High trans selectivity in the copper bis(oxazoline)-catalyzed asymmetric cyclopropanation of olefins by (trimethylsilyl)diazomethane
France, MB
Milojevich, AK
Stitt, TA
Kim, AJ
[J]. TETRAHEDRON LETTERS, 2003, 44 (52) : 9287 - 9290
[2] Hadasch A, 1997, B SOC CHIM FR, V134, P1025
[3] HADASCH A, 1994, J CHEM SOC CHEM COMM, P1799
[4] Catalytic cyclopropanation with iron(II) complexes
Hamaker, CG
Mirafzal, GA
Woo, LK
[J]. ORGANOMETALLICS, 2001, 20 (24) : 5171 - 5176
[5] Methyltrioxorhenium catalyzed oxidation of 1,2-diols to 1,2-diketones using hydrogen peroxide as oxidant
Jain, SL
Sharma, VB
Sain, B
[J]. TETRAHEDRON LETTERS, 2004, 45 (06) : 1233 - 1235
[6] Copper-catalyzed imination of pyridines using PhI=NTs as nitrene precursor
Jain, SL
Sharma, VB
Sain, B
[J]. TETRAHEDRON LETTERS, 2003, 44 (23) : 4385 - 4387
[7] Aziridination of alkenes using N-iodo-N-potassio-p-toluenesulphonamide as a nitrene precursor
Jain, SL
Sain, B
[J]. TETRAHEDRON LETTERS, 2003, 44 (03) : 575 - 577
[8] An unconventional cobalt-catalyzed aerobic oxidation of tertiary nitrogen compounds to N-oxides
Jain, SL
Sain, B
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (11) : 1265 - 1267
[9] Ruthenium catalyzed oxidation of tertiary nitrogen compounds with molecular oxygen:: an easy access to N-oxides under mild conditions
Jain, SL
Sain, B
[J]. CHEMICAL COMMUNICATIONS, 2002, (10) : 1040 - 1041
[10] Cobalt phthalocyaninetetrasulphonamide catalyzed aerobic oxidation of α-hydroxyketones:: an efficient and simple synthesis of α-diketones
Jain, SL
Sain, B
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 176 (1-2) : 101 - 104

← 1 2 3 →