A new addition to the Phillipsite family of molecular sieves: A divalent metal-ion-framework substituted microporous aluminophosphate (DAF-8)

被引:7
|
作者
Barrett, PA
Sankar, G
Stephenson, R
Catlow, CRA
Thomas, JM
Jones, RH
Teat, SJ
机构
[1] Davy Faraday Res Lab, London WLS 4BS, England
[2] Univ Keele, Sch Chem & Phys, Keele ST5 5BG, Staffs, England
[3] SERC, Daresbury Lab, CCLRC, Warrington WA4 4AD, Cheshire, England
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1016/j.solidstatesciences.2006.02.009
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
By adding Substantial amounts of either Co(II) or Zn(II) salts to a gel composed of Al2O3, P2O5 and the organic template 1,4-diaminocyclohexane, the tendency to yield layered aluminophosphates (AIPOs) is tilted in favour of the production of three-dimensional microporous MAIPOs: in particular, phase-pure samples of a novel Phillipsite structure (designated Davy-Faraday number 8, DAF-8) are formed. (c) 2006 Elsevier SAS. All rights reserved.
引用
收藏
页码:337 / 341
页数:5
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