Silver deposited on graphitic carbon nitride prepared under microwave irradiation for photodegradation of 2-chlorophenol

被引:0
作者
Azami, M. S. [1 ,2 ]
Jalil, A. A. [3 ]
Nawawi, W., I [2 ]
Mamat, C. R. [1 ]
Izzudin, N. M. [3 ]
机构
[1] Univ Teknol Malaysia, Fac Sci, Johor Baharu 81310, Johor, Malaysia
[2] Univ Teknol MARA, Photocatalysis Lab, FSG, Arau 02600, Perlis, Malaysia
[3] Univ Teknol Malaysia, Fac Engn, Sch Chem & Energy Engn, Johor Baharu 81310, Johor, Malaysia
关键词
Silver; Graphitic carbon nitride; Microwave; 2-chlorophenol; Visible light; PHOTOCATALYTIC ACTIVITY; NANOPARTICLES; G-C3N4; DECOMPOSITION; ENHANCEMENT; DEGRADATION;
D O I
10.1016/j.matpr.2022.06.193
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
2-chlorophenol (2-CP) has been extensively utilized in various industries such as agricultural, cosmetic, paper, and biocide. The 2-CP has become a dangerous pollutant that can cause serious water pollution. Photocatalytic degradation is one of the effective destructive methods to remove 2-CP pollutant. Silver deposited on graphitic carbon nitride (Ag/g-C3N4) was prepared using the solid-state method without using any solvent and treated under microwave irradiation. The photocatalysts were characterized using UV-Vis DRS, N2 adsorption-desorption, FTIR, and FESEM analyses. The result shows that the bandgap energy was drastically narrowed after introducing Ag on g-C3N4. The deposited Ag on g-C3N4 provided a high performance (80%) of 2-CP after irradiation for 240 min under visible light. The enhancement of photodegradation was significantly influenced by the well dispersion of the Ag on the surface g-C3N4 and the low bandgap energy induced the synergistic effect between g-C3N4 and Ag. The existence of Ag metal on g-C3N4 prepared under microwave markedly can enhance a great potential photocatalyst for organic pollutants wastewater treatment.Copyright (c) 2022 Elsevier Ltd. All rights reserved. Selection and peer-review under responsibility of the scientific committee of the 8th International Con-ference on Solid State Science & Technology (8thICSSST 2021).
引用
收藏
页码:4068 / 4072
页数:5
相关论文
共 26 条
[1]   Improved visible-light activities of g-C3N4 nanosheets by co-modifying nano-sized SnO2 and Ag for CO2 reduction and 2,4-dichlorophenol degradation [J].
Ali, Wajid ;
Zhang, Xuliang ;
Zhang, Xinxin ;
Ali, Sharafat ;
Zhao, Lina ;
Shaheen, Shabana ;
Jing, Liqiang .
MATERIALS RESEARCH BULLETIN, 2020, 122
[2]   Mineralization of 2-chlorophenol by sequential electrochemical reductive dechlorination and biological processes [J].
Angel Arellano-Gonzalez, Miguel ;
Gonzalez, Ignacio ;
Texier, Anne-Claire .
JOURNAL OF HAZARDOUS MATERIALS, 2016, 314 :181-187
[3]   Influence of the nitrogen pots from graphitic carbon nitride with the presence of wrinkled silica-titania for photodegradation enhancement of 2-chlorophenol [J].
Azami, M. S. ;
Jalil, A. A. ;
Aziz, F. F. A. ;
Hassan, N. S. ;
Mamat, C. R. ;
Izzudin, N. M. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2023, 48 (17) :6532-6545
[4]   Green carbonaceous material-fibrous silica-titania composite photocatalysts for enhanced degradation of toxic 2-chlorophenol [J].
Azami, M. S. ;
Jalil, A. A. ;
Hassan, N. S. ;
Hussain, I ;
Fauzi, A. A. ;
Aziz, M. A. A. .
JOURNAL OF HAZARDOUS MATERIALS, 2021, 414
[5]   Formation of an amorphous carbon nitride/titania composite for photocatalytic degradation of RR4 dye [J].
Azami, M. S. ;
Ismail, K. ;
Ishak, M. A. M. ;
Zuliahani, A. ;
Hamzah, S. R. ;
Nawawi, W., I .
JOURNAL OF WATER PROCESS ENGINEERING, 2020, 35
[6]   Tuning of the electronic band structure of fibrous silica titania with g-C3N4 for efficient Z-scheme photocatalytic activity [J].
Azami, M. S. ;
Jalil, A. A. ;
Hitam, C. N. C. ;
Hassan, N. S. ;
Mamat, C. R. ;
Adnan, R. H. ;
Chanlek, N. .
APPLIED SURFACE SCIENCE, 2020, 512
[7]   Formation of predominant interstitial N-TiO2 using physical preparation under microwave irradiation for Reactive Red 4 dye removal [J].
Azami, M. S. ;
Nawawi, W. I. ;
Shukri, D. S. M. .
DESALINATION AND WATER TREATMENT, 2017, 92 :172-180
[8]   Simultaneous photocatalytic reduction of hexavalent chromium and oxidation of p-cresol over AgO decorated on fibrous silica zirconia [J].
Aziz, F. F. A. ;
Jalil, A. A. ;
Hassan, N. S. ;
Fauzi, A. A. ;
Azami, M. S. .
ENVIRONMENTAL POLLUTION, 2021, 285
[9]   Catalytic decomposition of 2-chlorophenol using an ultrasonic-assisted Fe3O4-TiO2@MWCNT system: Influence factors, pathway and mechanism study [J].
Dobaradaran, Sina ;
Nodehi, Ramin Nabizadeh ;
Yaghmaeian, Kamyar ;
Jaafari, Jalil ;
Niari, Maryam Hazrati ;
Bharti, Arvind Kumar ;
Agarwal, Shilpi ;
Gupta, Vinod Kumar ;
Azari, Ali ;
Shariatifar, Nabi .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2018, 512 :172-189
[10]   Ag nanoparticles loaded on porous graphitic carbon nitride with enhanced photocatalytic activity for degradation of phenol [J].
Han, Zhenwei ;
Wang, Nan ;
Fan, Hai ;
Ai, Shiyun .
SOLID STATE SCIENCES, 2017, 65 :110-115