Perfluorinated Alcohols and Acids Induce Coacervation in Aqueous Solutions of Amphiphiles

被引：33

作者：

Khaledi, Morteza G. ^{[1
]}

Jenkins, Samuel I. ^{[1
]}

Liang, Shuang ^{[1
]}

机构：

[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

来源：

LANGMUIR | 2013年 / 29卷 / 08期

关键词：

ANIONIC SURFACTANT MIXTURES; PHASE-SEPARATION; 2-PHASE SYSTEMS; CATIONIC GEMINI; PEPTIDES; PROTEINS; TRIFLUOROETHANOL; COMPLEXATION; BEHAVIOR;

D O I：

10.1021/la303035h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have discovered that water-miscible perfluorinated alcohols and acids (FA) can induce simple and complex coacervation in aqueous solutions of a wide range of amphiphilic molecules such as synthetic surfactants, phospholipids, and bile salts as well as polyelectrolytes. This unique phenomenon seems to be nearly ubiquitous, especially for complex coacervate systems composed of mixed catanionic amphiphiles. In addition, coacervation and aqueous phase separation were observed over a wide range of surfactants concentrations and for different mole fractions of the oppositely charged amphiphile.

引用

页码：2458 / 2464

页数：7

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