Rhodium(III)-Catalyzed C-C Coupling between Arenes and Aziridines by C-H Activation

被引：132

作者：

Li, Xingwei ^{[1
]}

Yu, Songjie ^{[1
]}

Wang, Fen ^{[1
]}

Wan, Boshun ^{[1
]}

Yu, Xinzhang ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 09期

关键词：

aziridines; CC coupling; CH activation; rhodium; N BOND FORMATION; OXIDATIVE ANNULATION; EFFICIENT CATALYST; VERSATILE; ARYLATION; ARYL; ALKYNES; FUNCTIONALIZATION; OLEFINATION; AMIDATION;

D O I：

10.1002/anie.201209887

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Making C-C from C-H: [{RhCp*Cl2}2]/AgSbF 6 (Cp*=pentamethylcyclopentadienyl) can regioselectively catalyze the C-C coupling of arenes with aziridines by a C-H activation pathway. An eight-membered rhodacyclic intermediate resulting from the insertion of the Rh-C bond into the aziridine was isolated. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2577 / 2580

页数：4

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