On the problem of the tetrafluoroborate ion state in complexes with nitrogen-containing organic bases

被引：4

作者：

Chebotarev, AN ^{[1
]}

Shestakova, MV ^{[1
]}

Shcherbakova, TM ^{[1
]}

机构：

[1] Mechnikov Univ, UA-270100 Odessa, Ukraine

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2002年 / 28卷 / 02期

关键词：

Physical Chemistry; Metal Atom; Tetrafluoroborate; Organic Basis; Strong Organic Basis;

D O I：

10.1023/A:1014288219106

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Using a number of Cu(II), Zn(II), and Cd(II) tetrafluoroborate complexes with nitrogen-containing organic bases as examples, the possible existence of two states of the BF4- ion, namely, the "half-coordination" and counter-ion states, was studied. It was found that in [ML2(BF4)(2)] complexes with strong organic bases (L), the "half-coordination" of the anion exists. As the electron-donating ability of the ligand increases, the interaction between the tetrafluoroborate ion and the metal atom becomes more efficient.

引用

页码：131 / 134

页数：4

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