Vacuum Electrochemistry Approach to Investigate Electrical Double-Layer Capacitances of Ionic Liquid for Epitaxial Thin-Film Electrodes of TiO2and SrO on Niobium-Doped (001)SrTiO3

被引:2
作者
Takahashi, Chika [1 ]
Kanai, Mariko [1 ]
Maruyama, Shingo [1 ]
Matsumoto, Yuji [1 ]
机构
[1] Tohoku Univ, Dept Appl Chem, Sch Engn, Aoba Ku, 6-6-07 Aramaki Aza Aoba, Sendai, Miyagi 9808579, Japan
关键词
ionic liquids; electrical double layer; oxide electrodes; vacuum electrochemistry; pulsed laser deposition; WATER; CONDUCTIVITY; DIFFRACTION; TRANSISTORS; MICROSCOPY; INTERFACE; GROWTH;
D O I
10.1002/celc.202000620
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The Cover Featureillustrates a new potentiality of vacuum electrochemistry approach to investigate well-defined ionic liquid/oxide interfaces when vacuum electrochemistry meets pulsed laser deposition (PLD). The electric double layer (EDL) capacitance of ionic liquid is carefully investigated under vacuum for oxide electrodes of not only single-crystal SrTiO3, but also the subsequently PLD-grown SrO and anatase TiO(2)epitaxial films. The direct comparison of these EDL capacitance values allows us to find out that the EDL capacitance is quite sensitive to the kinds of oxide interfaces; the ionicity of the oxides is proposed as a possible key to the interpretation of the present finding. More information can be found in theArticle by C. Takahashi et al.
引用
收藏
页码:3253 / 3259
页数:7
相关论文
共 42 条
  • [1] Study of average valence and valence electron distribution of several oxides using X-ray photoelectron spectra
    Ding, L. L.
    Wu, L. Q.
    Ge, X. S.
    Du, Y. N.
    Qian, J. J.
    Tang, G. D.
    Zhong, W.
    [J]. RESULTS IN PHYSICS, 2018, 9 : 866 - 870
  • [2] Electric-double-layer field-effect transistors with ionic liquids
    Fujimoto, Takuya
    Awaga, Kunio
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (23) : 8983 - 9006
  • [3] Ionic liquid-based electrolytes for "beyond lithium" battery technologies
    Giffin, Guinevere A.
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (35) : 13378 - 13389
  • [4] The interface between Au(111) and an ionic liquid
    Gnahm, M.
    Pajkossy, T.
    Kolb, D. M.
    [J]. ELECTROCHIMICA ACTA, 2010, 55 (21) : 6212 - 6217
  • [5] INVESTIGATION OF PRECIPITATE FORMATION ON LASER-ABLATED YBA2CU3O7-DELTA THIN-FILMS
    GONG, JP
    KAWASAKI, M
    FUJITO, K
    TSUCHIYA, R
    YOSHIMOTO, M
    KOINUMA, H
    [J]. PHYSICAL REVIEW B, 1994, 50 (05): : 3280 - 3287
  • [6] STUDY OF PLATINUM-ELECTRODES BY MEANS OF THIN-LAYER ELECTROCHEMISTRY AND LOW-ENERGY ELECTRON-DIFFRACTION .1. ELECTRODE SURFACE-STRUCTURE AFTER EXPOSURE TO WATER AND AQUEOUS-ELECTROLYTES
    ISHIKAWA, RM
    HUBBARD, AT
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1976, 69 (03): : 317 - 338
  • [7] Effect of water adsorption on microscopic friction force on SrTiO3(001)
    Iwahori, K
    Watanabe, S
    Kawai, M
    Kobayashi, K
    Yamada, H
    Matsushige, K
    [J]. JOURNAL OF APPLIED PHYSICS, 2003, 93 (06) : 3223 - 3227
  • [8] Ionic liquid/ZnO(0001) single crystal and epitaxial film interfaces studied through a combination of electrochemical measurements and a pulsed laser deposition process under vacuum
    Kanai, Mariko
    Watanabe, Ko
    Maruyama, Shingo
    Matsumoto, Yuji
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2019, 21 (45) : 25506 - 25512
  • [9] ATOMIC CONTROL OF THE SRTIO3 CRYSTAL-SURFACE
    KAWASAKI, M
    TAKAHASHI, K
    MAEDA, T
    TSUCHIYA, R
    SHINOHARA, M
    ISHIYAMA, O
    YONEZAWA, T
    YOSHIMOTO, M
    KOINUMA, H
    [J]. SCIENCE, 1994, 266 (5190) : 1540 - 1542
  • [10] Effect of A-site cation ordering on the magnetoelectric properties in [(LaMnO3)m/(SrMnO3)m]n artificial superlattices -: art. no. 144418
    Koida, T
    Lippmaa, M
    Fukumura, T
    Itaka, K
    Matsumoto, Y
    Kawasaki, M
    Koinuma, H
    [J]. PHYSICAL REVIEW B, 2002, 66 (14) : 1 - 6