Site-selective Suzuki-Miyaura reactions of 2,6-dichlorobenzoxazole

被引：7

作者：

Hamdy, Aws M. ^{[1
]}

Eleya, Nadi ^{[1
]}

Mohammed, Hamid H. ^{[1
,2
]}

Patonay, Tamas ^{[3
]}

Spannenberg, Anke ^{[4
]}

Langer, Peter ^{[1
,4
]}

机构：

[1] Univ Rostock, Inst Chem, D-18059 Rostock, Germany

[2] Univ Al Mustansiriyah, Dept Organ Chem, Baghdad, Iraq

[3] Univ Debrecen, Dept Organ Chem, H-4032 Debrecen, Hungary

[4] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

TETRAHEDRON | 2013年 / 69卷 / 08期

关键词：

Benzoxazole; Site-selectivity; Palladium; Catalysis; Suzuki-Miyaura reaction; CROSS-COUPLING REACTIONS; PARALLEL SYNTHESIS; BENZOXAZOLES; 2-ARYLBENZOXAZOLES; ARYLATION; CHLORIDES; BROMIDES; LIBRARY; BASES;

D O I：

10.1016/j.tet.2012.11.021

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Suzuki-Miyaura reactions of 2,6-dichlorobenzoxazole provide a convenient access to arylated benzoxazoles. The reactions proceed with excellent site-selectivity in favour of position 2, due to electronic reasons. (c) 2012 Elsevier Ltd. All rights reserved.

引用

收藏

页码：2081 / 2086

页数：6

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