Highly selective synthesis of diphenylmethane with acidic ionic liquids

被引：24

作者：

Cui, SH ^{[1
]}

Lu, B ^{[1
]}

Cai, QH ^{[1
]}

Cai, XJ ^{[1
]}

Li, XM ^{[1
]}

Xiao, X ^{[1
]}

Hou, LJ ^{[1
]}

Han, YY ^{[1
]}

机构：

[1] Harbin Normal Univ, Dept Chem, Harbin 150080, Peoples R China

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2006年 / 45卷 / 05期

关键词：

D O I：

10.1021/ie0510268

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Synthesis of diphenylmethane (DPM) from benzene and benzyl chloride with acidic ionic liquids, such as (C2H5)(3)NHCl-AlCl3, (C2H5)(3)NHCl-ZnCl2, (C2H5)(3)NHCl-FeCl3, and (C2H5)(3)NHCl-CuCl2, as catalysts was investigated. The results showed that (C2H5)(3)NHCl-AlCl3 is a highly efficient catalyst. Both the yield and the selectivity of DPM reached up to 100% in the presence of (C2H5)(3)NHCI-AlCl3 as catalyst, when the reaction was carried out at ambient conditions.

引用

页码：1571 / 1574

页数：4

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