Thermodynamic characteristics of the formation of silver(I) complexes with crown ether in an aqueous solution

被引：1

作者：

Belevantsev, V. I. ^{[1
]}

Robov, A. M. ^{[2
]}

Fedorov, V. A. ^{[2
]}

Batalina, L. S. ^{[2
]}

Kovaleva, M. A. ^{[2
]}

机构：

[1] Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Siberian State Technol Univ, Krasnoyarsk 660049, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2012年 / 86卷 / 10期

关键词：

Potentiometry; complexation; crown ether18C6; complexes of silver(I); Gibbs energy;

D O I：

10.1134/S0036024412100032

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Thermodynamic characteristics of complex formation of silver (I) with crown ether 18C6 are determined by polythermal potentiometry in the temperature range of 15-35A degrees C. The applicability of the regression analysis of experimental data is demonstrated, with allowance for the mutual compensation of the temperature effect on the enthalpy and entropy contributions to the Gibbs energy of complexation.

引用

页码：1533 / 1536

页数：4

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