Preparation of amino-modified hydroxyapatite and its uranium adsorption properties

被引:33
作者
Feng, Yurun [1 ]
Ma, Baoshan [3 ]
Guo, Xue [2 ]
Sun, Haibin [2 ]
Zhang, Yujun [1 ]
Gong, Hongyu [1 ]
机构
[1] Shandong Univ, Key Lab Liquid Solid Struct Evolut & Proc Mat, Minist Educ, Jinan 250061, Shandong, Peoples R China
[2] Shandong Univ Technol, Sch Mat Sci & Engn, Zibo 255049, Peoples R China
[3] Shandong Sanshan Highway Engn Supervis Consulting, Liaocheng, Peoples R China
基金
中国国家自然科学基金;
关键词
Hydroxyapatite; Amino modified; Uranium; Adsorption; AQUEOUS-SOLUTIONS; REMOVAL; CARBON; SORBENT; SILICA; ORE;
D O I
10.1007/s10967-018-6357-4
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The amino-hydroxyapatite (HAP-NH2) was synthesized by grafted amino functional groups onto hydroxyapatite. The uranium adsorption performance of HAP-NH2 was studied under different conditions. The results indicated that HAP-NH2 possessed high adsorption capacity (96mgg(-1)), wide pH values range (2-8) and fast adsorption rate (20min). The adsorption kinetic and adsorption isotherm models of HAP-NH2 revealed that the uranium adsorption process was belonged to chemical adsorption. Furthermore, the main forces between uranium ions and HAP-NH2 were attributed to hydroxyl, amino and phosphorous functional groups.
引用
收藏
页码:437 / 446
页数:10
相关论文
共 28 条
[1]   Polyacrylamide-hydroxyapatite composite: Preparation, characterization and adsorptive features for uranium and thorium [J].
Baybas, Demet ;
Ulusoy, Ulvi .
JOURNAL OF SOLID STATE CHEMISTRY, 2012, 194 :1-8
[2]   Hydroxyapatite modified with silica used for sorption of copper(II) [J].
Bogya, Erzsebet-Sara ;
Barabas, Reka ;
Csavdari, Alexandra ;
Dejeu, Valentina ;
Baldea, Ioan .
CHEMICAL PAPERS, 2009, 63 (05) :568-573
[3]  
Chai LY, 2017, INT J ENVIRON SCI TE, V15, P1
[4]   Remediation of Uranium-contaminated Groundwater by Sorption onto Hydroxyapatite Derived from Catfish Bones [J].
Chattanathan, S. A. ;
Clement, T. P. ;
Kanel, S. R. ;
Barnett, M. O. ;
Chatakondi, N. .
WATER AIR AND SOIL POLLUTION, 2013, 224 (02)
[5]  
Chen C.M, 2009, METAL MINE, V39, P135
[6]   Removal of U(VI) from Aqueous Solution by Amino Functionalized Flake Graphite Prepared by Plasma Treatment [J].
Duan, Shengxia ;
Wang, Yanan ;
Liu, Xia ;
Shao, Dadong ;
Hayat, Tawwar ;
Alsaedi, Ahmed ;
Li, Jiaxing .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (05) :4073-4085
[7]   Adsorption of Cd (II) and Zn (II) from aqueous solutions using magnetic hydroxyapatite nanoparticles as adsorbents [J].
Feng, Yuan ;
Gong, Ji-Lai ;
Zeng, Guang-Ming ;
Niu, Qiu-Ya ;
Zhang, Hui-Ying ;
Niu, Cheng-Gang ;
Deng, Jiu-Hua ;
Yan, Ming .
CHEMICAL ENGINEERING JOURNAL, 2010, 162 (02) :487-494
[8]  
Freundlich H, 1906, Z PHYS CHEM-STOCH VE, V57, P385
[9]   Phosphoryl functionalized mesoporous silica for uranium adsorption [J].
Guo, Xue ;
Feng, Yurun ;
Ma, Li ;
Gao, Dezhi ;
Jing, Jie ;
Yu, Jincheng ;
Sun, Haibin ;
Gong, Hongyu ;
Zhang, Yujun .
APPLIED SURFACE SCIENCE, 2017, 402 :53-60
[10]   Uptake of Sr2+ and Co2+ into Biogenic Hydroxyapatite: Implications for Biomineral Ion Exchange Synthesis [J].
Handley-Sidhu, S. ;
Renshaw, J. C. ;
Moriyama, S. ;
Stolpe, B. ;
Mennan, C. ;
Bagheriasl, S. ;
Yong, P. ;
Stamboulis, A. ;
Paterson-Beedle, M. ;
Sasaki, K. ;
Pattrick, R. A. D. ;
Lead, J. R. ;
Macaskie, L. E. .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2011, 45 (16) :6985-6990