Nickel ferrite nanoenabled graphene oxide (NiFe2O4@GO) as photoactive nanocomposites for water treatment

被引:30
作者
Bayantong, Allen Rhay B. [1 ]
Shih, Yu-Jen [2 ]
Dong, Cheng-Di [3 ]
Garcia-Segura, Sergi [4 ]
de Luna, Mark Daniel G. [1 ,5 ]
机构
[1] Univ Philippines Diliman, Natl Grad Sch Engn, Environm Engn Program, Quezon City 1101, Philippines
[2] Natl Sun Yat Sen Univ, Inst Environm Engn, Kaohsiung 81157, Taiwan
[3] Natl Kaohsiung Univ Sci & Technol, Dept Marine Environm Engn, Kaohsiung 81157, Taiwan
[4] Arizona State Univ, Nanosyst Engn Res Ctr Nanotechnol Enabled Water T, Sch Sustainable Engn & Built Environm, Tempe, AZ 85287 USA
[5] Univ Philippines Diliman, Dept Chem Engn, Quezon City 1101, Philippines
关键词
Advanced oxidation process; Graphene nanocomposite; Photocatalysis; UV irradiation; Wastewater treatment; VISIBLE-LIGHT; WASTE-WATER; PHOTOCATALYTIC OXIDATION; TIO2; PHOTOCATALYSIS; SOLAR; DEGRADATION; REDUCTION; HETEROJUNCTION; ACETAMINOPHEN; CONTAMINANTS;
D O I
10.1007/s11356-020-10545-1
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Nanocomposite materials can enhance the capabilities of water treatment processes such as photocatalysis. In this work, novel light-driven nanocatalysts were synthesized by using nickel ferrite (NiFe2O4) to nanoenable graphene oxide (GO) substrates. GO is an emerging 2D nanomaterial with high conductivity and adsorption properties. Moreover, the electric properties of GO improve photocatalytic performance by promoting charge carrier separation. Results of the characterization of the nickel ferrite nanoenabled graphene oxide (NiFe2O4@GO) nanocomposites demonstrate that homogeneous and stable photocatalysts were produced. The as-synthesized nanocatalysts enabled complete decolorization of the colored water matrix in short irradiation times of 150 min using minimal catalyst loading at 0.5 g L-1. The selective hook and destroy mechanism reduced the competitive effect of co-existing ions in solution. Furthermore, the use of specific scavengers helped to elucidate the degradation mechanisms of organic dye methylene blue by NiFe2O4@GO nanocomposites.
引用
收藏
页码:5472 / 5481
页数:10
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