Photocatalytic activity of TiO2 prepared by adding polyethyleneglycol

被引:2
作者
Kuo, Chao-Yin [1 ]
Lin, Han-Yu [2 ]
机构
[1] Natl Yunlin Univ Sci & Technol, Dept Safety Hlth & Environm Engn, Touliu 640, Yunlin, Taiwan
[2] Natl Yunlin Univ Sci & Technol, Grad Sch Engn Sci & Technol, Touliu 640, Yunlin, Taiwan
来源
REACTION KINETICS AND CATALYSIS LETTERS | 2009年 / 96卷 / 01期
关键词
Bisphenol A; photocatalytic activity; TiO2; polyethyleneglycol; BISPHENOL-A DEGRADATION; ADVANCED OXIDATION; AQUEOUS; 4-NITROPHENOL; CATALYTIC OZONATION; HYDROXYL RADICALS; WATER; DECOLORIZATION; IRRADIATION; ZEOLITES; REACTOR;
D O I
10.1007/s11144-009-5405-z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
TiO2 was produced by the sol-gel method with the addition of polyethyleneglycol (PEG) to study the effects of the molecular weight and the addition percentage of PEG. Bisphenol A (BPA) degradation rate constants were highest as 3.07, 4.02 and 4.23 h(-1) at PEG addition percentages of 10%, 5% and 0.5%. After 12 h reaction, the total organic carbon (TOC) reductions in UV/TiO2, UV/TiO2/PEG(200, 10%), UV/TiO2/PEG(600, 5%) and UV/TiO2/PEG(3500, 0.5%) systems were 44%, 24%, 19% and 23%, in order. The results demonstrated that adding an appropriate percentage of PEG to the TiO2 preparation processes increased the BPA degradation and TOC reduction.
引用
收藏
页码:147 / 155
页数:9
相关论文
共 29 条
[11]   Photocatalytic degradation of reactive black 5 in aqueous solutions: Effect of operating conditions and coupling with ultrasound irradiation [J].
Kritikos, Demetrios E. ;
Xekoukoulotakis, Nikolaos P. ;
Psillakis, Elefteria ;
Mantzavinos, Dionissios .
WATER RESEARCH, 2007, 41 (10) :2236-2246
[12]   Removal of phenol and 4-chlorophenol by surfactant-modified natural zeolite [J].
Kuleyin, Ayse .
JOURNAL OF HAZARDOUS MATERIALS, 2007, 144 (1-2) :307-315
[13]   Enhancement of photocatalytic activity in UV-illuminated tin dioxode/aluminum oxide system in aqueous 4-nitrophenol [J].
Kuo, Chao-Yin .
REACTION KINETICS AND CATALYSIS LETTERS, 2007, 92 (02) :337-343
[14]   Effect of coupled semiconductor system treating aqueous 4-nitrophenol [J].
Kuo, CY ;
Lin, HY .
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2004, 39 (08) :2113-2127
[15]   Degradation of endocrine disrupting bisphenol A by 254 nm irradiation in different water matrices and effect on yeast cells [J].
Neamtu, Mariana ;
Frimmel, Fritz H. .
WATER RESEARCH, 2006, 40 (20) :3745-3750
[16]   Nanoclusters of silver doped in zeolites as photocatalysts [J].
Patterson, Howard H. ;
Gomez, Robert S. ;
Lu, Haiyan ;
Yson, Renante L. .
CATALYSIS TODAY, 2007, 120 (02) :168-173
[17]   Solar photocatalytic degradation of azo dye:: comparison of photocatalytic efficiency of ZnO and TiO2 [J].
Sakthivel, S ;
Neppolian, B ;
Shankar, MV ;
Arabindoo, B ;
Palanichamy, M ;
Murugesan, V .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2003, 77 (01) :65-82
[18]   EXPLOITING THE INTERPARTICLE ELECTRON-TRANSFER PROCESS IN THE PHOTOCATALYZED OXIDATION OF PHENOL, 2-CHLOROPHENOL AND PENTACHLOROPHENOL - CHEMICAL EVIDENCE FOR ELECTRON AND HOLE TRANSFER BETWEEN COUPLED SEMICONDUCTORS [J].
SERPONE, N ;
MARUTHAMUTHU, P ;
PICHAT, P ;
PELIZZETTI, E ;
HIDAKA, H .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1995, 85 (03) :247-255
[19]   Preparation and photo-catalytic activity of Fe-TiO2 thin films prepared by sol-gel clip coating [J].
Sonawane, RS ;
Kale, BB ;
Dongare, MK .
MATERIALS CHEMISTRY AND PHYSICS, 2004, 85 (01) :52-57
[20]   A review of the environmental fate, effects, and exposures of bisphenol A [J].
Staples, CA ;
Dorn, PB ;
Klecka, GM ;
O'Block, ST ;
Harris, LR .
CHEMOSPHERE, 1998, 36 (10) :2149-2173